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Alcohols Phenols and Ethers question

2023 · 29 Jan · Shift 2 · Q4
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Alcohols Phenols and Ethers question

2023 · 29 Jan · Shift 2 · Q4

JEE MainChemistryAlcohols Phenols and EthersMCQ+4 / −1
A solution of CrO5\mathrm{Cr O_5}CrO5​ in amyl alcohol has a ‾\underline{\hspace{2cm}}​ colour.
  1. A
    Yellow
  2. B
    Orange-Red
  3. C
    Green
  4. D
    Blue
View written solutionFree

Correct answer: D

  1. Identify the species

    The compound CrO5\mathrm{CrO_5}CrO5​ is known as chromium peroxide.

  2. Recall its characteristic colour

    CrO5\mathrm{CrO_5}CrO5​ is an unstable blue-coloured compound. It is formed when hydrogen peroxide reacts with acidified dichromate/chromate solution.

  3. Behaviour in organic solvents

    Since CrO5\mathrm{CrO_5}CrO5​ is unstable in water, it is extracted into organic solvents such as amyl alcohol, ether, etc., where it shows an intense blue colour.

  4. Evaluate options

    • A: Yellow →\rightarrow→ Incorrect
    • B: Orange-Red →\rightarrow→ Incorrect
    • C: Green →\rightarrow→ Incorrect
    • D: Blue →\rightarrow→ Correct
  5. Final answer

    A solution of CrO5\mathrm{CrO_5}CrO5​ in amyl alcohol has blue colour.

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