Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Atoms and Nuclei question

2008 · Shift 1 · Q64
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Advanced
  3. /Physics
  4. /Atoms and Nuclei
  5. /2008 · Shift 1 · Q64

Atoms and Nuclei question

2008 · Shift 1 · Q64

JEE AdvancedPhysicsAtoms and NucleiMCQ+3 / −1
In a mixture of H - He +^++ gas (He +^++ is singly ionized He atom), H atoms and He +^++ ions are excited to their respective first excited states. Subsequently, H atoms transfer their total excitation energy to He +^++ ions (by collisions). Assume that the Bohr model of atom is exactly valid.The quantum number n of the state finally populated in He +^++ ions is :
  1. A
    2
  2. B
    3
  3. C
    4
  4. D
    5
View written solutionFree

Correct answer: C

Step-by-step Solution:

  1. Understand the Bohr Model Energy Formula The energy of an electron in the n-th orbit for a hydrogen-like atom with atomic number Z is given by the Bohr model formula: En=−13.6Z2n2 eVE_n = -13.6 \frac{Z^2}{n^2} \text{ eV}En​=−13.6n2Z2​ eV where nnn is the principal quantum number.

  2. Calculate the Excitation Energy of the Hydrogen Atom For a Hydrogen atom (H), the atomic number is Z=1Z=1Z=1.

    • The ground state energy (n=1) is: E1,H=−13.61212=−13.6 eVE_{1,H} = -13.6 \frac{1^2}{1^2} = -13.6 \text{ eV}E1,H​=−13.61212​=−13.6 eV
    • The first excited state (n=2) is the state to which the H atoms are initially excited. Its energy is: E2,H=−13.61222=−13.64=−3.4 eVE_{2,H} = -13.6 \frac{1^2}{2^2} = -\frac{13.6}{4} = -3.4 \text{ eV}E2,H​=−13.62212​=−413.6​=−3.4 eV
    • The total excitation energy of the H atom is the energy difference between the first excited state and the ground state. This is the amount of energy that the H atom will transfer when it de-excites to its ground state. ΔEH=E2,H−E1,H=(−3.4 eV)−(−13.6 eV)=10.2 eV\Delta E_H = E_{2,H} - E_{1,H} = (-3.4 \text{ eV}) - (-13.6 \text{ eV}) = 10.2 \text{ eV}ΔEH​=E2,H​−E1,H​=(−3.4 eV)−(−13.6 eV)=10.2 eV
  3. Determine the Initial Energy of the He+^++ ion For a singly ionized Helium ion (He+^++), the atomic number is Z=2Z=2Z=2.

    • The He+^++ ions are also initially in their first excited state, which corresponds to n=2n=2n=2.
    • The energy of the He+^++ ion in its first excited state is: Einitial,He+=E2,He+=−13.62222=−13.644=−13.6 eVE_{initial, He^+} = E_{2,He^+} = -13.6 \frac{2^2}{2^2} = -13.6 \frac{4}{4} = -13.6 \text{ eV}Einitial,He+​=E2,He+​=−13.62222​=−13.644​=−13.6 eV
  4. Calculate the Final Energy of the He+^++ ion after Collision The problem states that the H atom transfers its total excitation energy (10.2 eV) to the He+^++ ion upon collision. The He+^++ ion, which is already in its first excited state, absorbs this energy.

    • The final energy of the He+^++ ion will be its initial energy plus the energy it absorbed: Efinal,He+=Einitial,He++ΔEHE_{final, He^+} = E_{initial, He^+} + \Delta E_HEfinal,He+​=Einitial,He+​+ΔEH​ Efinal,He+=−13.6 eV+10.2 eV=−3.4 eVE_{final, He^+} = -13.6 \text{ eV} + 10.2 \text{ eV} = -3.4 \text{ eV}Efinal,He+​=−13.6 eV+10.2 eV=−3.4 eV
  5. Find the Quantum Number (n) of the Final State of the He+^++ ion Now we need to find the quantum number 'n' that corresponds to this final energy for the He+^++ ion.

    • Using the Bohr energy formula for He+^++ (Z=2Z=2Z=2): En,He+=−13.622n2=−54.4n2 eVE_{n,He^+} = -13.6 \frac{2^2}{n^2} = -\frac{54.4}{n^2} \text{ eV}En,He+​=−13.6n222​=−n254.4​ eV
    • We set this equal to the final energy we calculated: Efinal,He+=En,He+E_{final, He^+} = E_{n,He^+}Efinal,He+​=En,He+​ −3.4 eV=−54.4n2 eV-3.4 \text{ eV} = -\frac{54.4}{n^2} \text{ eV}−3.4 eV=−n254.4​ eV
    • Solving for n2n^2n2: n2=−54.4−3.4=54.43.4=16n^2 = \frac{-54.4}{-3.4} = \frac{54.4}{3.4} = 16n2=−3.4−54.4​=3.454.4​=16
    • Taking the square root to find n: n=16=4n = \sqrt{16} = 4n=16​=4

Thus, the quantum number of the state finally populated in He+^++ ions is 4.

PreviousNext

More from Atoms and Nuclei

  • In a mixture of H - He + gas (He + is singly ionized He atom), H atoms and He + ions are excited to their respective first excited states. Subsequently, H atoms transfer their total excitation energy to He + ions (by…2008 · MCQ
  • In a mixture of H - He + gas (He + is singly ionized He atom), H atoms and He + ions are excited to their respective first excited states. Subsequently, H atoms transfer their total excitation energy to He + ions (by…2008 · MCQ
  • A radioactive sample S1 having activity of 5 μ Ci has twice the number of nuclei as another sample S2 which has an activity of 10 μ Ci. The half lives of S1 and S2 can be :2008 · MCQ
  • In the option given below, let E denote the rest mass energy of a nucleus and n a neutron. The correct option is2007 · MCQ
  • The largest wavelength in the ultraviolet region of the hydrogen spectrum is 122 nm. The smallest wavelength in the infrared region of the hydrogen spectrum (to the nearest integer) is2007 · MCQ
  • List-I shows various functional dependencies of energy (E) on the atomic number (Z). Energies associated with certain phenomena are given in List-II. Choose the option that describes the correct match between the entries in List-I to… Includes table2025 · MCQ
  • A particle of mass m is moving in a circular orbit under the influence of the central force F(r)=−kr, corresponding to the potential energy V(r)=kr2/2, where k is a positive force constant and r is the radial distance from…2024 · Multiple correct
  • List-I shows different radioactive decay processes and List-II provides possible emitted particles. Match each entry in List-I with an appropriate entry from List-II, and choose the correct option. Includes table2023 · MCQ