JEE AdvancedPhysicsAtoms and NucleiMCQ+3 / −1
The largest wavelength in the ultraviolet region of the hydrogen spectrum is 122 nm. The smallest wavelength in the infrared region of the hydrogen spectrum (to the nearest integer) is
- A802 nm
- B823 nm
- C1882 nm
- D1648 nm
View written solutionFree
Correct answer: B
Step-by-step Solution:
-
Analyze the given information about the ultraviolet (UV) region.
- The emission spectrum of hydrogen in the ultraviolet region corresponds to the Lyman series, where the electron transitions to the final state .
- The wavelength of the emitted photon is given by the Rydberg formula: where is the Rydberg constant.
- The largest wavelength () corresponds to the smallest energy transition. For the Lyman series, this occurs for the transition from the lowest possible initial state, , to the final state .
- We are given that the largest wavelength in the UV region is 122 nm. So, for the transition from to :
-
Analyze the question about the infrared (IR) region.
- The emission spectra in the infrared region correspond to the Paschen series (), Brackett series (), Pfund series (), and so on.
- We need to find the smallest wavelength () in the entire infrared region. This corresponds to the highest possible energy transition in the IR region.
- The energy of a transition to a final state is maximized when the electron comes from . This is known as the series limit. The energy of such a transition is .
- To get the highest energy transition in the entire IR region, we must choose the smallest possible value of for an IR series, which is (the Paschen series).
- Therefore, the smallest wavelength in the IR region corresponds to the transition from to .
- Let this wavelength be . Using the Rydberg formula:
-
Calculate the unknown wavelength.
- We can find by taking the ratio of equation (1) and equation (2) to eliminate the Rydberg constant .
- Divide equation (2) by equation (1):
- Now, solve for :
-
Select the nearest integer option.
- The calculated wavelength is 823.5 nm.
- The question asks for the answer to the nearest integer. The options are 802 nm, 823 nm, 1882 nm, and 1648 nm.
- The value 823.5 nm is closest to 823 nm among the given options. The slight difference is likely due to the problem statement using a rounded value of 122 nm for the Lyman-alpha line (its actual value is closer to 121.5 nm).
Therefore, the smallest wavelength in the infrared region of the hydrogen spectrum is approximately 823 nm.
More from Atoms and Nuclei
- List-I shows various functional dependencies of energy on the atomic number . Energies associated with certain phenomena are given in List-II. Choose the option that describes the correct match between the entries in List-I to… Includes table2025 · MCQ
- A particle of mass is moving in a circular orbit under the influence of the central force , corresponding to the potential energy , where is a positive force constant and is the radial distance from…2024 · Multiple correct
- List-I shows different radioactive decay processes and List-II provides possible emitted particles. Match each entry in List-I with an appropriate entry from List-II, and choose the correct option. Includes table2023 · MCQ
- In a radioactive decay process, the activity is defined as , where is the number of radioactive nuclei at time . Two radioactive sources, and have same activity at time . At a later time, the…2023 · Numerical
- The minimum kinetic energy needed by an alpha particle to cause the nuclear reaction in a laboratory frame is (in .…2022 · Numerical
- The binding energy of nucleons in a nucleus can be affected by the pairwise Coulomb repulsion. Assume that all nucleons are uniformly distributed inside the nucleus. Let the binding energy of a proton be and the binding energy…2022 · Multiple correct
- In a radioactive decay chain reaction, nucleus decays into nucleus. The ratio of the number of to number of particles emitted in this process is …2022 · Numerical
- A heavy nucleus Q of half-life 20 minutes undergoes alpha-decay with probability of 60% and beta-decay with probability of 40%. Initially, the number of Q nuclei is 1000. The number of alpha-decays of Q in the first one hour is2021 · MCQ