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Structure of Atom question

2012 · Shift 1 · Q6
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Structure of Atom question

2012 · Shift 1 · Q6

JEE AdvancedChemistryStructure of AtomMCQ+4 / −1
The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is [α0\alpha_0α0​ is Bohr radius]
  1. A
    h24π2mα02{h^2 \over {4{\pi ^2}m\alpha _0^2}}4π2mα02​h2​
  2. B
    h216π2mα02{h^2 \over {16{\pi ^2}m\alpha _0^2}}16π2mα02​h2​
  3. C
    h232π2mα02{h^2 \over {32{\pi ^2}m\alpha _0^2}}32π2mα02​h2​
  4. D
    h264π2mα02{h^2 \over {64{\pi ^2}m\alpha _0^2}}64π2mα02​h2​
View written solutionFree

Correct answer: C

Step-by-step Derivation:

  1. Identify the Goal: The question asks for the kinetic energy (KE) of an electron in the second Bohr orbit (n=2n=2n=2) of a hydrogen atom, expressed in terms of Planck's constant (hhh), the electron's mass (mmm), and the Bohr radius (\\{\alpha_0}\\}).

  2. Recall Key Formulas:

    • The kinetic energy of an electron is given by KE=12mv2KE = \frac{1}{2}mv^2KE=21​mv2, where mmm is the mass and vvv is the velocity of the electron.
    • According to Bohr's model, the angular momentum of an electron in the n-th orbit is quantized: L=mvrn=nh2πL = mvr_n = \frac{nh}{2\pi}L=mvrn​=2πnh​, where rnr_nrn​ is the radius of the n-th orbit.
    • The radius of the n-th Bohr orbit for a hydrogen atom (Z=1Z=1Z=1) is given by rn=n2α0r_n = n^2 \alpha_0rn​=n2α0​, where \\{\alpha_0}\\} is the Bohr radius (radius of the first orbit, n=1n=1n=1).
  3. Express Velocity in terms of other variables: From the angular momentum quantization condition, we can solve for the velocity vvv: v=nh2πmrnv = \frac{nh}{2\pi m r_n}v=2πmrn​nh​

  4. Substitute the velocity into the Kinetic Energy formula: Substitute the expression for vvv into the KE formula: KE=12mv2=12m(nh2πmrn)2KE = \frac{1}{2}m v^2 = \frac{1}{2}m \left(\frac{nh}{2\pi m r_n}\right)^2KE=21​mv2=21​m(2πmrn​nh​)2 KE=12m(n2h24π2m2rn2)KE = \frac{1}{2}m \left(\frac{n^2 h^2}{4\pi^2 m^2 r_n^2}\right)KE=21​m(4π2m2rn2​n2h2​) KE=n2h28π2mrn2KE = \frac{n^2 h^2}{8\pi^2 m r_n^2}KE=8π2mrn2​n2h2​

  5. Substitute the radius rnr_nrn​ with its expression in terms of \\{\alpha_0}\\}: Now, substitute rn=n2α0r_n = n^2 \alpha_0rn​=n2α0​ into the expression for KE: KE=n2h28π2m(n2α0)2KE = \frac{n^2 h^2}{8\pi^2 m (n^2 \alpha_0)^2}KE=8π2m(n2α0​)2n2h2​ KE=n2h28π2m(n4α02)KE = \frac{n^2 h^2}{8\pi^2 m (n^4 \alpha_0^2)}KE=8π2m(n4α02​)n2h2​ Simplifying the expression by canceling n2n^2n2 from the numerator and denominator, we get a general formula for KE in the n-th orbit: KEn=h28π2mn2α02KE_n = \frac{h^2}{8\pi^2 m n^2 \alpha_0^2}KEn​=8π2mn2α02​h2​

  6. Calculate the Kinetic Energy for the second Bohr orbit (n=2n=2n=2): The question specifically asks for the KE in the second Bohr orbit, so we set n=2n=2n=2: KEn=2=h28π2m(2)2α02KE_{n=2} = \frac{h^2}{8\pi^2 m (2)^2 \alpha_0^2}KEn=2​=8π2m(2)2α02​h2​ KEn=2=h28π2m(4)α02KE_{n=2} = \frac{h^2}{8\pi^2 m (4) \alpha_0^2}KEn=2​=8π2m(4)α02​h2​ KEn=2=h232π2mα02KE_{n=2} = \frac{h^2}{32\pi^2 m \alpha_0^2}KEn=2​=32π2mα02​h2​

  7. Compare with the given options: The calculated value, h232π2mα02{h^2 \over {32{\pi ^2}m\alpha _0^2}}32π2mα02​h2​, matches option C.

  • A: {h^2 \over {4{\pi ^2}m\alpha _0^2}}}
  • B: {h^2 \over {16{\pi ^2}m\alpha _0^2}}}
  • C: {h^2 \over {32{\pi ^2}m\alpha _0^2}}}
  • D: {h^2 \over {64{\pi ^2}m\alpha _0^2}}}

Thus, the correct option is C.

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