JEE AdvancedChemistryPractical Organic ChemistryNumerical+3 / −1
The weight percentage of hydrogen in , formed in the following reaction sequence, is .
[Given: Atomic mass of ]
[Given: Atomic mass of ]Numerical answer
View written solutionFree
Correct answer: 1.30TO1.32
-
Identify the reaction sequence from the practical organic chemistry context
In this standard sequence:
- Aniline is first diazotised to benzene diazonium chloride.
- On treatment with sulfurous acid / sulfur dioxide in presence of copper salts, the diazonium salt gives benzenesulfonyl chloride.
- Benzenesulfonyl chloride then reacts with aniline to form the sulfonamide derivative used in the Hinsberg-type reaction sequence.
Thus, is N-phenyl benzenesulfonamide.
-
Write the molecular formula of
Benzenesulfonyl chloride has formula:
Reaction with aniline replaces Cl by :
Therefore,
-
Calculate molar mass of
-
Calculate percentage of hydrogen
Mass of hydrogen in one mole of :
Hence,
-
Compare with stored answer
The derived value is:
The stored correct answer is to , which does not match.
So the stored answer appears inconsistent with the standard reaction/product interpretation.
More from Practical Organic Chemistry
- Match the compounds in List-I with the appropriate observations in List-II and choose the correct option. Includes table Includes diagram2025 · MCQ
- The reaction of 4-methyloct-1-ene with in the presence of gives two isomeric bromides in a ratio, with a combined…2023 · Numerical
- Consider the following reaction. On estimation of bromine in of using Carius method, the amount of formed (in ) is . [Given: Atomic mass of … Includes diagram2022 · Numerical