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P Block Elements question

2016 · Shift 1 · Q14
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P Block Elements question

2016 · Shift 1 · Q14

JEE AdvancedChemistryP Block ElementsMultiple correct+4 / −2
The crystalline form of borax has.
  1. A
    tetranuclear [B4O5(OH)4]2−[B_4O_5(OH)_4]^{2-}[B4​O5​(OH)4​]2− unit
  2. B
    all boron atoms in the same plane
  3. C
    equal number of sp2 and sp3 hybridised boron atoms
  4. D
    one terminal hydroxide per boron atom
View written solutionFree

Correct answer: A, C, D

  1. Identify the crystalline borax anion

    Crystalline borax is sodium tetraborate decahydrate: Na2B4O7⋅10H2O\mathrm{Na_2B_4O_7\cdot 10H_2O}Na2​B4​O7​⋅10H2​O

    In the crystalline state, the tetraborate ion is better represented as: [B4O5(OH)4]2−[B_4O_5(OH)_4]^{2-}[B4​O5​(OH)4​]2−

    So, the borax crystal contains a tetranuclear borate unit.

    Hence, Option A is correct.

  2. Examine the structure of [B4O5(OH)4]2−[B_4O_5(OH)_4]^{2-}[B4​O5​(OH)4​]2−

    In this anion:

    • Two boron atoms are trigonal planar  (sp2)\, (sp^2)(sp2)
    • Two boron atoms are tetrahedral  (sp3)\, (sp^3)(sp3)

    Therefore, the number of sp2sp^2sp2 and sp3sp^3sp3 hybridised boron atoms is equal.

    Hence, Option C is correct.

  3. Check whether all boron atoms lie in the same plane

    Since two boron atoms are tetrahedral (sp3sp^3sp3), the entire set of boron atoms cannot all be coplanar.

    Tetrahedral geometry is non-planar, so all boron atoms are not in the same plane.

    Hence, Option B is incorrect.

  4. Check the number of terminal hydroxyl groups

    The anion is: [B4O5(OH)4]2−[B_4O_5(OH)_4]^{2-}[B4​O5​(OH)4​]2−

    There are 4 hydroxyl groups and 4 boron atoms, so effectively there is one terminal hydroxyl group per boron atom.

    Hence, Option D is correct.

  5. Final derived answer

    Correct options are: A, C, D\boxed{A,\ C,\ D}A, C, D​

  6. Comparison with stored correct answer

    Stored correct answer: A, C, D

    This matches the derived answer.

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