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Gaseous State question

2009 · Shift 2 · Q13
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Gaseous State question

2009 · Shift 2 · Q13

JEE AdvancedChemistryGaseous StateNumerical+3 / −1
At 400 K, the root mean square (rms) speed of a gas X (molecular weight = 40) is equal to the most probable speed of gas Y at 60 K. The molecular weight of the gas Y is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 4

  1. Write the required formulas

For a gas:

  • Root mean square speed: urms=3RTMu_{\text{rms}} = \sqrt{\frac{3RT}{M}}urms​=M3RT​​
  • Most probable speed: ump=2RTMu_{\text{mp}} = \sqrt{\frac{2RT}{M}}ump​=M2RT​​

Here, MMM is molar mass.

  1. Use the given condition

Given:

  • Gas XXX: MX=40M_X = 40MX​=40, TX=400 KT_X = 400\,\text{K}TX​=400K
  • Gas YYY: TY=60 KT_Y = 60\,\text{K}TY​=60K, MY=?M_Y = ?MY​=?

According to the question, urms(X)=ump(Y)u_{\text{rms}}(X) = u_{\text{mp}}(Y)urms​(X)=ump​(Y)

So, 3R(400)40=2R(60)MY\sqrt{\frac{3R(400)}{40}} = \sqrt{\frac{2R(60)}{M_Y}}403R(400)​​=MY​2R(60)​​

  1. Square both sides

3R(400)40=2R(60)MY\frac{3R(400)}{40} = \frac{2R(60)}{M_Y}403R(400)​=MY​2R(60)​

Cancel RRR: 3⋅40040=2⋅60MY\frac{3\cdot 400}{40} = \frac{2\cdot 60}{M_Y}403⋅400​=MY​2⋅60​

120040=120MY\frac{1200}{40} = \frac{120}{M_Y}401200​=MY​120​

30=120MY30 = \frac{120}{M_Y}30=MY​120​

  1. Solve for MYM_YMY​

MY=12030=4M_Y = \frac{120}{30} = 4MY​=30120​=4

  1. Final answer

The molecular weight of gas YYY is: 4\boxed{4}4​

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