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Compounds Containing Nitrogen question

2022 · Shift 1 · Q18
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  5. /2022 · Shift 1 · Q18

Compounds Containing Nitrogen question

2022 · Shift 1 · Q18

JEE AdvancedChemistryCompounds Containing NitrogenMCQ+3 / −1

Match the compounds in LIST-I with the observations in LIST-II, and choose the correct option.

List-I List-II
(I) Aniline
 (P) Sodium fusion extract of the compound on boiling with FeSO4\mathrm{FeSO}_{4}FeSO4​, followed by acidification with conc. H2SO4\mathrm{H}_{2} \mathrm{SO}_{4}H2​SO4​, gives Prussian blue color.
(II) ooo-Cresol (Q) Sodium fusion extract of the compound on treatment with sodium nitroprusside gives blood red color.
(III) Cysteine
 (R) Addition of the compound to a saturated solution of NaHCO3\mathrm{NaHCO}_{3}NaHCO3​ results in effervescence.
(IV) Caprolactam
 (S) The compound reacts with bromine water to give a white precipitate.
(T) Treating the compound with neutral FeCl3\mathrm{FeCl}_{3}FeCl3​ solution produces violet color.

  1. A
    I→P,Q\mathrm{I} \rightarrow \mathrm{P}, \mathrm{Q}I→P,Q; II →S;III→Q,R\rightarrow \mathrm{S} ; \mathrm{III} \rightarrow \mathrm{Q}, \mathrm{R}→S;III→Q,R; IV →P\rightarrow \mathrm{P}→P
  2. B
    I→P\mathrm{I} \rightarrow \mathrm{P}I→P; II →R\rightarrow \mathrm{R}→R, S\mathrm{S}S; III →R\rightarrow \mathrm{R}→R; IV→Q,S\mathrm{IV} \rightarrow \mathrm{Q}, \mathrm{S}IV→Q,S
  3. C
    I→Q,S\mathrm{I} \rightarrow \mathrm{Q}, \mathrm{S}I→Q,S; II →P,T\rightarrow \mathrm{P}, \mathrm{T}→P,T; III →P\rightarrow \mathrm{P}→P; IV →S\rightarrow \mathrm{S}→S
  4. D
    I→P\mathrm{I} \rightarrow \mathrm{P}I→P, S; II →T\rightarrow \mathrm{T}→T; III →Q,R\rightarrow \mathrm{Q}, \mathrm{R}→Q,R; IV→P\mathrm{IV} \rightarrow \mathrm{P}IV→P
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