
- A-chloro--methylbenzene
- B-chlorotoluene
- C-methylchlorobenzene
- D-methyl--chlorobenzene
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Correct answer: A, B
-
Identify the structure
The compound is a benzene ring having two substituents:
- one chloro group,
- one methyl group,
These are placed at the para positions relative to each other, i.e. positions and .
-
Apply IUPAC naming rules
For a disubstituted benzene:
- Number the ring to give the lowest set of locants.
- If there is a tie, assign locant to the substituent that comes first in alphabetical order.
Here, the substituents are:
- chloro
- methyl
Alphabetically, chloro comes before methyl. So the correct IUPAC name is:
Hence, Option A is correct.
-
Check retained/common IUPAC name
The compound can also be named as a derivative of toluene:
- toluene = methylbenzene
- chloro group is at the para position
So the name is:
Hence, Option B is also correct.
-
Examine Option C: -methylchlorobenzene
This is not the proper IUPAC form. In benzene derivatives with two substituents, both substituents should be cited separately with benzene as parent, giving: not "-methylchlorobenzene".
So Option C is incorrect.
-
Examine Option D: -methyl--chlorobenzene
Though the locants are , in a tie the substituent cited first alphabetically should get locant . Since chloro comes before methyl, the correct numbering must be: not
So Option D is incorrect.
-
Final answer
The correct IUPAC/accepted names are:
- A. -chloro--methylbenzene
- B. -chlorotoluene
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