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Aldehydes Ketones and Carboxylic Acids question

2024 · Shift 2 · Q14
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Aldehydes Ketones and Carboxylic Acids question

2024 · Shift 2 · Q14

JEE AdvancedChemistryAldehydes Ketones and Carboxylic AcidsNumerical+3 / −1
An organic compound P\mathbf{P}P with molecular formula C9H18O2\mathrm{C}_9 \mathrm{H}_{18} \mathrm{O}_2C9​H18​O2​ decolorizes bromine water and also shows positive iodoform test. P\mathbf{P}P on ozonolysis followed by treatment with H2O2\mathrm{H}_2 \mathrm{O}_2H2​O2​ gives Q\mathbf{Q}Q and R\mathbf{R}R. While compound Q\mathbf{Q}Q shows positive iodoform test, compound R\mathbf{R}R does not give positive iodoform test. Q\mathbf{Q}Q and R\mathbf{R}R on oxidation with pyridinium chlorochromate (PCC) followed by heating give S\mathbf{S}S and T\mathbf{T}T, respectively. Both S\mathbf{S}S and T\mathbf{T}T show positive iodoform test. Complete copolymerization of 500 moles of Q\mathbf{Q}Q and 500 moles of R\mathbf{R}R gives one mole of a single acyclic copolymer U\mathbf{U}U. [Given, atomic mass: H=1,C=12,O=16\mathrm{H}=1, \mathrm{C}=12, \mathrm{O}=16H=1,C=12,O=16]Sum of number of oxygen atoms in S\mathbf{S}S and T\mathbf{T}T is ‾\underline{\hspace{2cm}}​.
Numerical answer
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