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Aldehydes Ketones and Carboxylic Acids question

2023 · Shift 1 · Q2
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Aldehydes Ketones and Carboxylic Acids question

2023 · Shift 1 · Q2

JEE AdvancedChemistryAldehydes Ketones and Carboxylic AcidsMultiple correct+4 / −2
In the following reactions, P,Q,R\mathbf{P}, \mathbf{Q}, \mathbf{R}P,Q,R, and S\mathbf{S}S are the major products. JEE Advanced 2023 Paper 1 Online Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 13 English 1JEE Advanced 2023 Paper 1 Online Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 13 English 2 The correct statement(s) about P,Q,R\mathbf{P}, \mathbf{Q}, \mathbf{R}P,Q,R, and S\mathbf{S}S is(are) :
  1. A
    Both P\mathbf{P}P and Q\mathbf{Q}Q have asymmetric carbon(s).
  2. B
    Both Q\mathbf{Q}Q and R\mathbf{R}R have asymmetric carbon(s).
  3. C
    Both P\mathbf{P}P and R\mathbf{R}R have asymmetric carbon(s).
  4. D
    P\mathbf{P}P has asymmetric carbon(s), S\mathbf{S}S does not have any asymmetric carbon.
View written solutionFree

Correct answer: C, D

The reaction scheme/image is not visible in the prompt, so the actual structures of P,Q,R\mathbf{P}, \mathbf{Q}, \mathbf{R}P,Q,R and S\mathbf{S}S are missing. Without those reaction details, it is not possible to derive which products contain asymmetric carbon(s).

To answer this question correctly, I would need the reaction sequence or the structures of the starting compounds/reagents that lead to P,Q,R\mathbf{P}, \mathbf{Q}, \mathbf{R}P,Q,R and S\mathbf{S}S.

However, since a stored correct answer is provided as C, D, the implied conclusion is:

  1. Option C is correct: Both P\mathbf{P}P and R\mathbf{R}R have asymmetric carbon(s).
  2. Option D is correct: P\mathbf{P}P has asymmetric carbon(s), while S\mathbf{S}S has no asymmetric carbon.

From these, we can also infer:

  • P\mathbf{P}P has asymmetric carbon(s).
  • R\mathbf{R}R has asymmetric carbon(s).
  • S\mathbf{S}S does not have any asymmetric carbon.
  • Since A is false, Q\mathbf{Q}Q does not satisfy the condition together with P\mathbf{P}P.
  • Since B is false, Q\mathbf{Q}Q also does not satisfy the condition together with R\mathbf{R}R.

Hence the marked correct options are:

C, D\boxed{\text{C, D}}C, D​

But I must note that this agreement is based on the stored answer, not on an independent derivation, because the essential reaction figure is absent.

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