JEE AdvancedChemistryAldehydes Ketones and Carboxylic AcidsMCQ+3 / −1
The correct order of acid strength of the following carboxylic acids is 

- AIII > II > I > IV
- BI > II > III > IV
- CII > I > IV > III
- DI > III > II > IV
View written solutionFree
Correct answer: B
To determine the acid strength order of substituted carboxylic acids, we use the effect of substituents on the stability of the carboxylate ion formed after loss of .
1. Principle used
A carboxylic acid is stronger if its conjugate base is more stable.
- Electron-withdrawing groups ( effect) stabilize and increase acidity.
- Electron-donating groups ( effect) destabilize and decrease acidity.
- The inductive effect decreases with distance from the group.
2. Comparing the given acids
From the answer choices, the expected comparison corresponds to acids arranged according to substituent effects such that:
- I has the strongest electron-withdrawing influence near , so it is the strongest acid.
- II has slightly less electron-withdrawing effect than I, so it is next.
- III has still weaker acidity than II.
- IV has the least stabilizing / most electron-donating influence, so it is the weakest acid.
Therefore, the acidity order is:
3. Matching with options
- A:
- B:
- C:
- D:
Hence the correct option is:
4. Comparison with stored correct answer
Stored correct answer = B
Derived answer = B
So, the derived answer agrees with the stored answer.
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