- A

- B

- C

- D

View written solutionFree
Correct answer: A
-
First reaction: Benzene with in presence of anhydrous
This is the Gattermann–Koch formylation of benzene. So benzene gives benzaldehyde. -
Reaction of benzaldehyde with
Benzaldehyde in presence of acetic anhydride and sodium acetate undergoes Perkin reaction to form cinnamic acid. Therefore, -
Check the transformation of to
reacts with , followed by heating with moist at .- adds bromine across the double bond of cinnamic acid to form a dibromo acid.
- Strong heating with moist causes further transformation leading to phenylpropiolic acid / related elimination product, consistent with the known behavior of cinnamic acid derivatives.
This step is not directly needed to identify , but it confirms that is an -unsaturated acid.
-
Reaction of with
Catalytic hydrogenation reduces the bond of cinnamic acid, but does not reduce the group under these conditions. This product is 3-phenylpropanoic acid. -
Treatment with
On heating, 3-phenylpropanoic acid undergoes intramolecular cyclization / Friedel-type cyclodehydration conditions to form the corresponding cyclic ketone, namely 1-indanone.The transformation is:
-
Hence, is
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Comparison with stored answer
The stored correct answer is A. Since , this matches option A.
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