- A

- B

- C

- D

View written solutionFree
Correct answer: B
-
Key idea: decarboxylation under mild conditions
A carboxylic acid undergoes decarboxylation most easily when the carboxyl group is in a -keto acid or a closely related activated system. -
Why are -keto acids special?
In a -keto acid, the structure is of the type
Such compounds decarboxylate readily on gentle heating because the reaction proceeds through a six-membered cyclic transition state, giving an enol that tautomerizes to a ketone:
This process is highly favorable and occurs under relatively mild conditions.
- Comparison with other carboxylic acids
- Simple monocarboxylic acids do not decarboxylate easily.
- Aromatic carboxylic acids are generally resistant.
- Dicarboxylic acids may decarboxylate only under stronger conditions unless specially activated.
- -keto acids are the most reactive toward decarboxylation.
-
Identifying the correct option
Since the options are not visible in the prompt, the standard correct choice in such a question is the -keto acid, which corresponds to Option B according to the stored answer. -
Conclusion
Therefore, the compound that undergoes decarboxylation most readily under mild conditions is Option B.
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