- Adichloromethane solution of -naphthol.
- Bacidic solution of -naphthol.
- Cneutral solution of -naphthol.
- Dalkaline solution of -naphthol.
View written solutionFree
Correct answer: D
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Principle of the dye test for phenols / naphthols
The dye test is based on azo coupling. First, an aromatic primary amine is converted into a diazonium salt, and then this diazonium salt couples with an activated aromatic ring such as phenol or naphthol to give a colored azo dye.
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Why medium matters for -naphthol
-Naphthol is a phenolic compound. In alkaline medium, it forms the naphthoxide ion:
The naphthoxide ion is much more reactive toward electrophilic azo coupling than neutral -naphthol.
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Effect of other media
- Acidic solution: phenol/naphthol remains protonated and is less reactive for coupling.
- Neutral solution: coupling is not as effective as in alkaline medium.
- Dichloromethane solution: not the required medium for the usual azo dye test.
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Conclusion
Therefore, for identification of -naphthol using the dye test, an alkaline solution is necessary.
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Option check
- A: Incorrect
- B: Incorrect
- C: Incorrect
- D: Correct
Hence, the correct answer is:
-
Comparison with stored correct answer
Stored correct answer = D
Derived answer = D
They match.
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