Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Alcohols Phenols and Ethers question

2014 · Shift 2 · Q5
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Advanced
  3. /Chemistry
  4. /Alcohols Phenols and Ethers
  5. /2014 · Shift 2 · Q5

Alcohols Phenols and Ethers question

2014 · Shift 2 · Q5

JEE AdvancedChemistryAlcohols Phenols and EthersMCQ+3 / −1
For the identification of β\betaβ-naphthol using dye test, it is necessary to use
  1. A
    dichloromethane solution of β\betaβ-naphthol.
  2. B
    acidic solution of β\betaβ-naphthol.
  3. C
    neutral solution of β\betaβ-naphthol.
  4. D
    alkaline solution of β\betaβ-naphthol.
View written solutionFree

Correct answer: D

  1. Principle of the dye test for phenols / naphthols

    The dye test is based on azo coupling. First, an aromatic primary amine is converted into a diazonium salt, and then this diazonium salt couples with an activated aromatic ring such as phenol or naphthol to give a colored azo dye.

  2. Why medium matters for β\betaβ-naphthol

    β\betaβ-Naphthol is a phenolic compound. In alkaline medium, it forms the naphthoxide ion:

    β-naphthol+OH−→β-naphthoxide ion+H2O\beta\text{-naphthol} + OH^- \rightarrow \beta\text{-naphthoxide ion} + H_2Oβ-naphthol+OH−→β-naphthoxide ion+H2​O

    The naphthoxide ion is much more reactive toward electrophilic azo coupling than neutral β\betaβ-naphthol.

  3. Effect of other media

    • Acidic solution: phenol/naphthol remains protonated and is less reactive for coupling.
    • Neutral solution: coupling is not as effective as in alkaline medium.
    • Dichloromethane solution: not the required medium for the usual azo dye test.
  4. Conclusion

    Therefore, for identification of β\betaβ-naphthol using the dye test, an alkaline solution is necessary.

  5. Option check

    • A: Incorrect
    • B: Incorrect
    • C: Incorrect
    • D: Correct

Hence, the correct answer is:

D: alkaline solution of β-naphthol\boxed{\text{D: alkaline solution of } \beta\text{-naphthol}}D: alkaline solution of β-naphthol​

  1. Comparison with stored correct answer

    Stored correct answer = D

    Derived answer = D

    They match.

PreviousNext

More from Alcohols Phenols and Ethers

  • The acidic hydrolysis of ether (X) shown below is fastest when Includes diagram2014 · MCQ
  • The compound that does NOT liberate CO2​, on treatment with aqueous sodium bicarbonate solution, is2013 · MCQ
  • Match the chemical conversions in List I with the appropriate reagents in List II and select the correct answer using the code given below the lists : Includes diagram2013 · MCQ
  • In the following reaction, the product/products formed is/are Includes diagram2013 · Multiple correct
  • The major product(s) of the following reaction is(are) Includes diagram2013 · Multiple correct
  • Match the reactions in Column I with appropriate types of steps/reactive intermediate involved in these reactions as given in Column II : Includes table Includes diagram2011 · MCQ
  • In the reaction the products are : Includes diagram2010 · MCQ
  • In the reaction The intermediate(s) is(are) Includes diagram2010 · Multiple correct