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2022

55 questions · IIT JAM
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2022

55 questions · IIT JAM

Chemistry55 questions
Organic Reaction Mechanism and Synthetic ApplicationsChemistry · 9 questionsMain Group ElementsChemistry · 3 questionsChemical Bonding and Shapes of MoleculesChemistry · 6 questionsBioinorganic ChemistryChemistry · 2 questionsChemical KineticsChemistry · 1 questionsAdsorptionChemistry · 1 questionsQualitative Organic AnalysisChemistry · 3 questionsSolid StateChemistry · 4 questionsTransition MetalsChemistry · 5 questionsSpectroscopyChemistry · 2 questionsAtomic and Molecular StructureChemistry · 3 questionsLiquid StateChemistry · 1 questionsGaseous StateChemistry · 1 questionsChemical and Phase EquilibriaChemistry · 3 questionsBasic Concepts and StereochemistryChemistry · 3 questionsChemical ThermodynamicsChemistry · 2 questionsAromatic and Heterocyclic ChemistryChemistry · 1 questionsAnalytical ChemistryChemistry · 2 questionsElectrochemistryChemistry · 2 questionsExtractions of MetalsChemistry · 1 questions
  1. Q1.The reagent required for the following transformation is
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · MCQ
  2. Q4.The major product formed in the following reaction K+O2​→ is
    Chemistry · Main Group Elements · MCQ
  3. Q5.Which one of the following options is best suited for effecting the transformation? HO CHO HO CO_{2}H
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · MCQ
  4. Q6.The structure of [XeF_{8}]^{2-} is
    Chemistry · Chemical Bonding and Shapes of Molecules · MCQ
  5. Q7.Among the following, the compound that forms the strongest hydrogen bond is
    Chemistry · Chemical Bonding and Shapes of Molecules · MCQ
  6. Q8.Among the following, the biomolecule with a direct metal-carbon bond is
    Chemistry · Bioinorganic Chemistry · MCQ
  7. Q9.For the reaction extH2​extPO2−​(aq)+extOH−(aq)→extHPO32−​(aq)+extH2​(g) the rate expression is k[extH2​extPO2−​][extOH−]2. If the concentration of extH2​extPO2−​ is doubled, the…
    Chemistry · Chemical Kinetics · MCQ
  8. Q10.The nature of interaction involved at the gas-solid interface in physisorption is
    Chemistry · Adsorption · MCQ
  9. Q11.The major product formed in the following reaction is Includes diagram
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · MCQ
  10. Q12.An organic compound having molecular formula C9​H10​O2​ exhibits the following spectral characteristics: 1H NMR: δ 9.72 (t, 1H), 7.1 (d, 2H), 6.7 (d, 2H), 3.8 (s, 3H), 3.6 (d, 2H) IR: ~1720 cm −1 The most probable structure of…
    Chemistry · Qualitative Organic Analysis · MCQ
  11. Q13.The major product formed in the reaction of (2S,3R)-2-chloro-3-phenylbutane with NaOEt in EtOH is
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · MCQ
  12. Q15.The reactivity of the enol derivatives towards benzaldehyde follows the order
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · MCQ
  13. Q16.All possible lattice types are observed in the
    Chemistry · Solid State · MCQ
  14. Q17.The structure types of B_{10}H_{10}^{2-} and B_{10}H_{14}, respectively, are
    Chemistry · Main Group Elements · MCQ
  15. Q18.The ground state and the maximum number of spin-allowed electronic transitions possible in a Co^{2+} tetrahedral complex, respectively, are
    Chemistry · Transition Metals · MCQ
  16. Q19.The correct statement about the geometries of BH_{2}^{+} and NH_{2}^{+} based on valence shell electron pair repulsion (VSEPR) theory is
    Chemistry · Chemical Bonding and Shapes of Molecules · MCQ
  17. Q20.The order of increasing CO stretching frequencies in [Co(CO)_{4}]^{-}, [Cu(CO)_{4}]^{+}, [Fe(CO)_{4}]^{2-} and [Ni(CO)_{4}] is
    Chemistry · Transition Metals · MCQ
  18. Q21.The reaction of 2,4-dinitrofluorobenzene with hydrazine produces a yellow orange solid **X** used for the identification of an organic functional group **G**. **X** and **G**, respectively, are
    Chemistry · Qualitative Organic Analysis · MCQ
  19. Q22.The stability of adducts H_{3}B·PF_{3}, H_{3}B·NMe_{3}, H_{3}B·CO, H_{3}B·OMe_{2} follows the order
    Chemistry · Chemical Bonding and Shapes of Molecules · MCQ
  20. Q23.The spacing between successive rotational energy levels of a diatomic molecule XY and its heavier isotopic analogue X'Y' varies with the rotational quantum number, J, as
    Chemistry · Spectroscopy · MCQ
  21. Q24.The ratio of the 2p → 1s transition energy in He + to that in the H atom is closest to
    Chemistry · Atomic and Molecular Structure · MCQ
  22. Q26.Capillary W contains water and capillary M contains mercury. The contact angles between the capillary wall and the edge of the meniscus at the air-liquid interface in W and M are θW​ and θM​, respectively. The contact angles…
    Chemistry · Liquid State · MCQ
  23. Q27.The Maxwell-Boltzmann distribution f( vx​) of one-dimensional velocities vx​ at temperature T is [Given: A is a normalization constant such that ∫−∞∞​f( vx​)d vx​=1 and kB​ is the Boltzmann constant]
    Chemistry · Gaseous State · MCQ
  24. Q28.The potential for a particle in a one-dimensional box is given as: V(x)=0 for 0≤x≤L, and V(x)=∞ elsewhere. The locations of the internal nodes of the eigenfunctions ψn​(x), n≥2, are [Given: m is an…
    Chemistry · Atomic and Molecular Structure · MCQ
  25. Q29.The number of CO stretching bands in the infrared spectrum of Fe(CO)_{5} is
    Chemistry · Transition Metals · MCQ
  26. Q30.The standard Gibbs free energy change for the reaction H_{2}O (g) → H_{2} (g) + ½ O_{2} (g) at 2500 K is +118 kJ mol^{-1}. The equilibrium constant for the reaction is [Given: R = 8.314 J K^{-1} mol^{-1}]
    Chemistry · Chemical and Phase Equilibria · MCQ
  27. Q31.Among the following, the reaction(s) that favor(s) the formation of the products at 25 °C is/are
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · Multiple correct
  28. Q32.Among the following, the correct statement(s) is/are:
    Chemistry · Basic Concepts and Stereochemistry · Multiple correct
  29. Q33.The compound(s) that participate(s) in Diels-Alder reaction with maleic anhydride is/are
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · Multiple correct
  30. Q34.Among the following, the suitable route(s) for the conversion of benzaldehyde to acetophenone is/are
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · Multiple correct
  31. Q35.The reaction involve(s)
    Chemistry · Transition Metals · Multiple correct
  32. Q36.The reason(s) for the lower stability of Si_{2}H_{6} compared to C_{2}H_{6} is/are
    Chemistry · Main Group Elements · Multiple correct
  33. Q37.For an N-atom nonlinear polyatomic gas, the constant volume molar heat capacity C_{v,m} has the expected value of 3(N - 1)R, based on the principle of equipartition of energy. The correct statement(s) about the measured value of C_{v,m}…
    Chemistry · Chemical Thermodynamics · Multiple correct
  34. Q38.Zinc containing enzyme(s) is/are
    Chemistry · Bioinorganic Chemistry · Multiple correct
  35. Q39.The conversion of ICl to ICl^{+} involve(s)
    Chemistry · Chemical Bonding and Shapes of Molecules · Multiple correct
  36. Q40.The common point defect(s) in a solid is/are
    Chemistry · Solid State · Multiple correct
  37. Q41.Among the following the number of aromatic compounds is ​. Includes diagram
    Chemistry · Aromatic and Heterocyclic Chemistry · Numerical
  38. Q42.The number of stereoisomers possible for the major product formed in the reaction is ​. Includes diagram
    Chemistry · Basic Concepts and Stereochemistry · Numerical
  39. Q43.The number of signals observed in the ^{1}H NMR spectrum of the compound is ​.
    Chemistry · Qualitative Organic Analysis · Numerical
  40. Q44.The reaction of 122 g of benzaldehyde with 108 g of phenylhydrazine gave 157 g of the product. The yield of the product is ​ %. (round off to the nearest integer)
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · Numerical
  41. Q45.The B–B bond order in B_{2} is ​.
    Chemistry · Chemical Bonding and Shapes of Molecules · Numerical
  42. Q46.The number of unpaired electrons in [Co(H_{2}O)_{6}]^{2+} is ​.
    Chemistry · Transition Metals · Numerical
  43. Q47.The number of significant figures in 5.0820 × 10^{2} is ​.
    Chemistry · Analytical Chemistry · Numerical
  44. Q48.The *d* spacing for the first-order X-ray (λ = 1.54 Å) diffraction event of metallic iron (*fcc*) at 2θ = 20.2° is ​ Å. (*round off to three decimal places*)
    Chemistry · Solid State · Numerical
  45. Q49.The volume fraction for an element in an *fcc* lattice is ​. (*round off to two decimal places*)
    Chemistry · Solid State · Numerical
  46. Q50.A steady current of 1.25 A is passed through an electrochemical cell for 1.5 h using a 12 V battery. The total charge, *Q*, drawn during this process is ​ Coulombs. (*round off to the nearest integer*)
    Chemistry · Electrochemistry · Numerical
  47. Q51.The specific rotation of optically pure (R)-1-phenylethylamine is +40 (neat, 20 °C). A synthetic sample of the same compound is shown to contain 4:1 mixture of (S)- and (R)-enantiomers. The specific rotation of the neat sample at 20 °C is ​…
    Chemistry · Basic Concepts and Stereochemistry · Numerical
  48. Q52.The number of β particles emitted in the nuclear reaction 92238​U→82206​Pb is ​.
    Chemistry · Analytical Chemistry · Numerical
  49. Q53.Iron is extracted from its ore via the reaction Fe2​O3​+3 CO→2 Fe+3 CO2​. The volume of CO (at STP) required to produce 1 kg of iron is ​ liters. *(round…
    Chemistry · Extractions of Metals · Numerical
  50. Q54.Total degeneracy (number of microstates) for a Ti^{3+} ion in spherical symmetry is ​.
    Chemistry · Atomic and Molecular Structure · Numerical
  51. Q55.A galvanic electrochemical cell made of Zn^{2+}/Zn and Cu^{2+}/Cu half-cells produces 1.10 V at 25 °C. The ratio of [Zn^{2+}] to [Cu^{2+}] is maintained at 1.0. The ΔG° for the reaction when 1.0 mol of Zn gets dissolved is ​…
    Chemistry · Electrochemistry · Numerical
  52. Q56.At constant volume, 1.0 kJ of heat is transferred to 2 moles of an ideal gas at 1 atm and 298 K. The final temperature of the ideal gas is ​ K. *(round off to one decimal place)* [Given: R = 8.314 J K^{-1} mol^{-1}]
    Chemistry · Chemical Thermodynamics · Numerical
  53. Q57.Two close lying bands in a UV spectrum occur at 274 nm and 269 nm. The magnitude of the energy gap between the two bands is ​ cm^{-1}. *(round off to the nearest integer)*
    Chemistry · Spectroscopy · Numerical
  54. Q58.The pH of an aqueous buffer prepared using CH_{3}COOH and CH_{3}COO^{-}Na^{+} is 4.80. The quantity [CH3​COOH][CH3​COO−]−[CH3​COOH]​ is ​. *(round off to…
    Chemistry · Chemical and Phase Equilibria · Numerical
  55. Q59.At constant temperature, 6.40 g of a substance dissolved in 78 g of benzene decreases the vapor pressure of benzene from 0.125 atm to 0.119 atm. The molar mass of the substance is ​ g mol^{-1}. *(round off to one…
    Chemistry · Chemical and Phase Equilibria · Numerical