IIT JAMChemistryTransition MetalsMCQ+2 / −0.67
The order of increasing CO stretching frequencies in [Co(CO)_{4}]^{-}, [Cu(CO)_{4}]^{+}, [Fe(CO)_{4}]^{2-} and [Ni(CO)_{4}] is
- A[Cu(CO)_{4}]^{+} < [Ni(CO)_{4}] < [Co(CO)_{4}]^{-} < [Fe(CO)_{4}]^{2-}
- B[Fe(CO)_{4}]^{2-} < [Co(CO)_{4}]^{-} < [Ni(CO)_{4}] < [Cu(CO)_{4}]^{+}
- C[Co(CO)_{4}]^{-} < [Fe(CO)_{4}]^{2-} < [Cu(CO)_{4}]^{+} < [Ni(CO)_{4}]
- D[Ni(CO)_{4}] < [Cu(CO)_{4}]^{+} < [Co(CO)_{4}]^{-} < [Fe(CO)_{4}]^{2-}
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Correct answer: B
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