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Some Basic Concepts of Organic Chemistry question

2024 · Q133
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Some Basic Concepts of Organic Chemistry question

2024 · Q133

NEETChemistrySome Basic Concepts of Organic ChemistryMCQ+4 / −1

On heating, some solid substances change from solid to vapour state without passing through liquid state. The technique used for the purification of such solid substances based on the above principle is known as

  1. A
    Crystallization
  2. B
    Sublimation
  3. C
    Distillation
  4. D
    Chromatography
View written solutionFree

Correct answer: B

The technique described in the question is known as sublimation. Sublimation is a process where a solid turns directly into a gas without passing through the intermediate liquid state. This physical change occurs under specific conditions of temperature and pressure and is characteristic of certain substances.

Option B: Sublimation is the correct answer because it directly describes the process of solid substances transforming into vapour without becoming liquid first. For example, substances like iodine, naphthalene, and dry ice (solid carbon dioxide) sublimate when heated under normal atmospheric conditions. Sublimation is not only a fascinating chemical process but is also exploited in various scientific and industrial applications, including purification of substances, where impurities do not sublimate and can thus be easily separated from the vaporized material.

The other options provided do not describe this process:

  • Crystallization (Option A) involves the formation of solid crystals from a homogeneous solution. It is typically used to purify solids wherein the impurities remain dissolved in the solvent.
  • Distillation (Option C) is a process used to separate mixtures based on differences in the conditions required to change the phase (liquid phase) of the components of the mixture. It does not involve direct transition from solid to gas.
  • Chromatography (Option D) is a method for separating components of a mixture based on differences in their movement through a stationary medium under the influence of a solvent or carrier gas. It does not involve the phase transition of solid to gas directly.
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