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Haloalkanes and Haloarenes question

2002 · Q126
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Haloalkanes and Haloarenes question

2002 · Q126

NEETChemistryHaloalkanes and HaloarenesMCQ+4 / −1
Reactivity order of halides for dehydrologenation is
  1. A
    R−F>R−Cl>R−Br>R−IR - F \gt R - Cl \gt R - Br \gt R - {\rm I}R−F>R−Cl>R−Br>R−I
  2. B
    R−I>R−Br>R−Cl>R−FR - {\rm I} \gt R - Br \gt R - Cl \gt R - FR−I>R−Br>R−Cl>R−F
  3. C
    R−I>R−Cl>R−Br>R−FR - {\rm I} \gt R - Cl \gt R - Br \gt R - FR−I>R−Cl>R−Br>R−F
  4. D
    R−F>R−I>R−Br>R−ClR - F \gt R - {\rm I} \gt R - Br \gt R - ClR−F>R−I>R−Br>R−Cl
View written solutionFree

Correct answer: B

atomic radii order :
I > Br > Cl > F

F, Cl, Br, I belongs to the same group orderly. Atomic radii go on increasing as the nuclear charge increases from top to bottom in a group. The decreasing order of bond length C – I > C – Br > C – Cl > C – F. The order of bond dissociation energy
R – F > R – Cl > R – Br > R – I. During dehydrohalogenation C – I bond breaks more easily than C – F bond.So reactivity order of halides

R−I>R−Br>R−Cl>R−FR - {\rm I} \gt R - Br \gt R - Cl \gt R - FR−I>R−Br>R−Cl>R−F

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