NEETChemistryCoordination CompoundsMCQ+4 / −1
Which statement is incorrect?
- ANi(CO)4 tetrahedral, paramagnetic
- BNi(CN)4 - square planar, diamagnetic
- CNi(CO)4 - tetrahedral, diamagnetic
- D[Ni(Cl)4]2 - tetrahedral, paramagnetic.
View written solutionFree
Correct answer: A
In Ni(CO)4-, Ni in zero oxidation state
Ni(0) = [Ar] 3d84s2

It has no unpaired electron so acts as diamagnetic and has tetrahedral structure.
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