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Aldehydes Ketones and Carboxylic Acids question

2013 · Q118
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Aldehydes Ketones and Carboxylic Acids question

2013 · Q118

NEETChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
The order of stability of the following tautomeric compounds is

NEET 2013 Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 63 English
  1. A
    II > I > III
  2. B
    II > III > I
  3. C
    I > II > III
  4. D
    III > II > I
View written solutionFree

Correct answer: D

Enolic form predominates in compounds containing two carbonyl groups separated by a –CH2 group. This is due to following two factors.

(i) Presence of conjugation which increases stability.

(ii) Formation of intramolecular hydrogen bond between enolic hydroxyl group and second carbonyl group which leads to stablisation of the molecule.

Hence the correct answer is III > II > I

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