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Aldehydes Ketones and Carboxylic Acids question

2010 · Q58
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Aldehydes Ketones and Carboxylic Acids question

2010 · Q58

NEETChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
Which one of the following compounds will be most readily dehydrated?
  1. A
    AIPMT 2010 Mains Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 57 English Option 1
  2. B
    AIPMT 2010 Mains Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 57 English Option 2
  3. C
    AIPMT 2010 Mains Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 57 English Option 3
  4. D
    AIPMT 2010 Mains Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 57 English Option 4
View written solutionFree

Correct answer: C

The intermediate is carbocation which is destabilised by C = O group (present on - carbon to the –OH group) in the first three cases. In (c), –hydrogen is more acidic which can be removed as water. Moreover, the positive charge on the intermediate carbocation is relatively away from the C = O group.

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