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Units and Measurements question

2019 · 11 Jan · Shift 1 · Q59
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Units and Measurements question

2019 · 11 Jan · Shift 1 · Q59

JEE MainPhysicsUnits and MeasurementsMCQ+4 / −1
The force of interaction between two atoms is given by F = αβ\alpha \betaαβ exp (−x2αkt)\left( { - {{{x^2}} \over {\alpha kt}}} \right)(−αktx2​); where x is the distance, k is the Boltzmann constant and T is temperature and α\alphaα and β\betaβ are two constants. The dimension of β\betaβ is :
  1. A
    M2L2T −-− 2
  2. B
    M2LT −-− 4
  3. C
    MLT −-− 4
  4. D
    M0L2LT −-− 4
View written solutionFree

Correct answer: B

  1. Given force law

The interaction force is

F=αβexp⁡(−x2αkT)F=\alpha\beta\exp\left(-\frac{x^2}{\alpha kT}\right)F=αβexp(−αkTx2​)

where:

  • xxx is distance,
  • kkk is Boltzmann constant,
  • TTT is temperature.

We need the dimensions of β\betaβ.


  1. Use the fact that the argument of exponential is dimensionless

For

exp⁡(−x2αkT)\exp\left(-\frac{x^2}{\alpha kT}\right)exp(−αkTx2​)

the quantity

x2αkT\frac{x^2}{\alpha kT}αkTx2​

must be dimensionless.

So,

[x2]=[αkT][x^2]=[\alpha kT][x2]=[αkT]

Now,

[x2]=L2[x^2]=L^2[x2]=L2

Also, kTkTkT has dimensions of energy, because Boltzmann constant kkk has dimensions energy per temperature. Thus,

[kT]=[energy]=ML2T−2[kT]=[\text{energy}]=ML^2T^{-2}[kT]=[energy]=ML2T−2

Hence,

[α]=L2ML2T−2=M−1T2[\alpha]=\frac{L^2}{ML^2T^{-2}}=M^{-1}T^2[α]=ML2T−2L2​=M−1T2
  1. Use dimensions of force

Since exponential is dimensionless,

[F]=[αβ][F]=[\alpha\beta][F]=[αβ]

Now,

[F]=MLT−2[F]=MLT^{-2}[F]=MLT−2

Therefore,

[β]=[F][α][\beta]=\frac{[F]}{[\alpha]}[β]=[α][F]​

Substitute [α]=M−1T2[\alpha]=M^{-1}T^2[α]=M−1T2:

[β]=MLT−2M−1T2[\beta]=\frac{MLT^{-2}}{M^{-1}T^2}[β]=M−1T2MLT−2​ [β]=M2LT−4[\beta]=M^2LT^{-4}[β]=M2LT−4
  1. Match with options
[β]=M2LT−4[\beta]=M^2LT^{-4}[β]=M2LT−4

This corresponds to Option B.


  1. Comparison with stored answer

Stored correct answer: B

Our derived answer: B

So, they agree.

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