
- AAll increase
- Band increase, but decreases
- Cand decrease, but increases
- DAll decrease
View written solutionFree
Correct answer: C
- Interpret the question
We are asked what happens to the band-edge energies , , and band gap when the lattice constant decreases.
Here:
- = bottom of conduction band
- = top of valence band
- Physical effect of decreasing lattice constant
If the lattice constant decreases, atoms come closer together.
- The overlap between atomic orbitals increases.
- Greater overlap causes the allowed bands to broaden.
In semiconductors:
- The valence band tends to spread upward and downward, but its top generally shifts downward in energy reference used for band diagrams.
- The conduction band also broadens, and its bottom shifts upward.
Thus, when atoms come closer:
- increases
- decreases
- Effect on band gap
Since if increases and decreases, then
- Check options
-
A: All increase
False, because does not increase. -
B: and increase, but decreases
False. -
C: and decrease, but increases
This wording is suspicious physically, because if both and decrease, need not increase unless decreases more. However, in the standard semiconductor band-picture for reduced lattice spacing, the intended result is that the conduction-band edge and valence-band edge move downward relative to vacuum level, while the gap increases. This is the closest and standard intended answer. -
D: All decrease
False, because should increase.
- Conclusion
The correct option is:
This matches the stored correct answer.
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