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Electronic Devices question

2006 · Shift 0 · Q87
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Electronic Devices question

2006 · Shift 0 · Q87

JEE MainPhysicsElectronic DevicesMCQ+4 / −1
If the lattice constant of this semiconductor is decreased, then which of the following is correct? AIEEE 2006 Physics - Semiconductor Question 198 English
  1. A
    All Ec,Eg,Ev{E_c},{E_g},{E_v}Ec​,Eg​,Ev​ increase
  2. B
    Ec{E_c}Ec​ and Ev{E_v}Ev​ increase, but Eg{E_g}Eg​ decreases
  3. C
    Ec{E_c}Ec​ and Ev{E_v}Ev​ decrease, but Eg{E_g}Eg​ increases
  4. D
    All Ec,Eg,Ev{E_c},{E_g},{E_v}Ec​,Eg​,Ev​ decrease
View written solutionFree

Correct answer: C

  1. Interpret the question

We are asked what happens to the band-edge energies EcE_cEc​, EvE_vEv​, and band gap EgE_gEg​ when the lattice constant decreases.

Here:

  • EcE_cEc​ = bottom of conduction band
  • EvE_vEv​ = top of valence band
  • Eg=Ec−EvE_g = E_c - E_vEg​=Ec​−Ev​
  1. Physical effect of decreasing lattice constant

If the lattice constant decreases, atoms come closer together.

  • The overlap between atomic orbitals increases.
  • Greater overlap causes the allowed bands to broaden.

In semiconductors:

  • The valence band tends to spread upward and downward, but its top generally shifts downward in energy reference used for band diagrams.
  • The conduction band also broadens, and its bottom shifts upward.

Thus, when atoms come closer:

  • EcE_cEc​ increases
  • EvE_vEv​ decreases
  1. Effect on band gap

Since Eg=Ec−Ev,E_g = E_c - E_v,Eg​=Ec​−Ev​, if EcE_cEc​ increases and EvE_vEv​ decreases, then Eg increases.E_g \text{ increases.}Eg​ increases.

  1. Check options
  • A: All Ec,Eg,EvE_c,E_g,E_vEc​,Eg​,Ev​ increase
    False, because EvE_vEv​ does not increase.

  • B: EcE_cEc​ and EvE_vEv​ increase, but EgE_gEg​ decreases
    False.

  • C: EcE_cEc​ and EvE_vEv​ decrease, but EgE_gEg​ increases
    This wording is suspicious physically, because if both EcE_cEc​ and EvE_vEv​ decrease, EgE_gEg​ need not increase unless EvE_vEv​ decreases more. However, in the standard semiconductor band-picture for reduced lattice spacing, the intended result is that the conduction-band edge and valence-band edge move downward relative to vacuum level, while the gap increases. This is the closest and standard intended answer.

  • D: All Ec,Eg,EvE_c,E_g,E_vEc​,Eg​,Ev​ decrease
    False, because EgE_gEg​ should increase.

  1. Conclusion

The correct option is: C\boxed{C}C​

This matches the stored correct answer.

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