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Atoms and Nuclei question

2023 · 1 Feb · Shift 1 · Q65
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  5. /2023 · 1 Feb · Shift 1 · Q65

Atoms and Nuclei question

2023 · 1 Feb · Shift 1 · Q65

JEE MainPhysicsAtoms and NucleiNumerical+4 / −1
A light of energy 12.75 eV12.75 ~\mathrm{eV}12.75 eV is incident on a hydrogen atom in its ground state. The atom absorbs the radiation and reaches to one of its excited states. The angular momentum of the atom in the excited state is xπ×10−17 eVs\frac{x}{\pi} \times 10^{-17} ~\mathrm{eVs}πx​×10−17 eVs. The value of xxx is ‾\underline{\hspace{2cm}}​ (use h=4.14×10−15 eVs,c=3×108 ms−1h=4.14 \times 10^{-15} ~\mathrm{eVs}, c=3 \times 10^{8} \mathrm{~ms}^{-1}h=4.14×10−15 eVs,c=3×108 ms−1 ).
Numerical answer
View written solutionFree

Correct answer: 828

  1. Energy levels of hydrogen

    For hydrogen atom, En=−13.6n2 eVE_n=-\frac{13.6}{n^2}\,\text{eV}En​=−n213.6​eV

    Initially, the atom is in ground state n=1n=1n=1, so E1=−13.6 eVE_1=-13.6\,\text{eV}E1​=−13.6eV

  2. Energy absorbed

    Incident light has energy 12.75 eV12.75\,\text{eV}12.75eV

    If the atom absorbs this photon and goes to level nnn, then En−E1=12.75E_n-E_1=12.75En​−E1​=12.75

    Substitute the hydrogen energy formula: −13.6n2−(−13.6)=12.75-\frac{13.6}{n^2}-(-13.6)=12.75−n213.6​−(−13.6)=12.75 13.6(1−1n2)=12.7513.6\left(1-\frac{1}{n^2}\right)=12.7513.6(1−n21​)=12.75

  3. Solve for nnn

    1−1n2=12.7513.61-\frac{1}{n^2}=\frac{12.75}{13.6}1−n21​=13.612.75​

    Now, 12.7513.6=0.9375=1516\frac{12.75}{13.6}=0.9375=\frac{15}{16}13.612.75​=0.9375=1615​

    Hence, 1−1n2=15161-\frac{1}{n^2}=\frac{15}{16}1−n21​=1615​ 1n2=116\frac{1}{n^2}=\frac{1}{16}n21​=161​ n2=16⇒n=4n^2=16 \Rightarrow n=4n2=16⇒n=4

    So the atom reaches the excited state with principal quantum number n=4n=4n=4.

  4. Angular momentum in Bohr model

    In the nnnth orbit, angular momentum is Ln=nh2πL_n=\frac{nh}{2\pi}Ln​=2πnh​

    For n=4n=4n=4, L=4h2π=2hπL=\frac{4h}{2\pi}=\frac{2h}{\pi}L=2π4h​=π2h​

    Given h=4.14×10−15 eV sh=4.14\times10^{-15}\,\text{eV s}h=4.14×10−15eV s

    Therefore, L=2×4.14×10−15πL=\frac{2\times4.14\times10^{-15}}{\pi}L=π2×4.14×10−15​ L=8.28×10−15π eV sL=\frac{8.28\times10^{-15}}{\pi}\,\text{eV s}L=π8.28×10−15​eV s

  5. Match with given form

    The question gives angular momentum as xπ×10−17 eV s\frac{x}{\pi}\times10^{-17}\,\text{eV s}πx​×10−17eV s

    So, xπ×10−17=8.28×10−15π\frac{x}{\pi}\times10^{-17}=\frac{8.28\times10^{-15}}{\pi}πx​×10−17=π8.28×10−15​

    Multiply both sides by π\piπ: x×10−17=8.28×10−15x\times10^{-17}=8.28\times10^{-15}x×10−17=8.28×10−15

    Hence, x=8.28×102=828x=8.28\times10^2=828x=8.28×102=828

  6. Final answer

    828\boxed{828}828​

  7. Comparison with stored answer

    Stored correct answer = 828828828

    This matches the derived answer.

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