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Thermodynamics question

2017 · Shift 0 · Q18
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Thermodynamics question

2017 · Shift 0 · Q18

JEE MainChemistryThermodynamicsMCQ+4 / −1
Given, C(graphite)+O2→CO2(g){C_{(graphite)}} + {O_2} \to C{O_2}(g)C(graphite)​+O2​→CO2​(g); ΔrHo{\Delta _r}{H^o}Δr​Ho= - 393.5 kJ mol-1 H2(g){{\rm H}_2}(g)H2​(g)+12O2(g)→H2O(l)ΔrHo{1 \over 2}{O_2}(g)\to {{\rm H}_2}{\rm O}(l){\Delta _r}{H^o}21​O2​(g)→H2​O(l)Δr​Ho= - 285.8 kJ mol-1 CO2(g)C{O_2}(g)CO2​(g)+2H2O(l)→CH4(g)2{{\rm H}_2}{\rm O}(l) \to C{H_4}(g)2H2​O(l)→CH4​(g)+2O2(g)ΔrHo2{O_2}(g){\Delta _r}{H^o}2O2​(g)Δr​Ho= + 890.3 kJ mol-1 Based on the above thermochemical equations, the value of ΔrHo{\Delta _r}{H^o}Δr​Ho at 298 K for the reaction C(graphite){C_{(graphite)}}C(graphite)​+2H2(g)→CH4(g)2{{\rm H}_2}(g) \to C{H_4}(g)2H2​(g)→CH4​(g) will be :
  1. A
    +144.0 kJ mol–1
  2. B
    – 74.8 kJ mol–1
  3. C
    -144.0 kJ mol–1
  4. D
    + 74.8 kJ mol–1
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