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Some Basic Concepts of Chemistry question

2025 · 22 Jan · Shift 2 · Q24
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Some Basic Concepts of Chemistry question

2025 · 22 Jan · Shift 2 · Q24

JEE MainChemistrySome Basic Concepts of ChemistryNumerical+4 / −1
20 mL of 2 M NaOH solution is added to 400 mL of 0.5 M NaOH solution. The final concentration of the solution is ‾×10−2M\underline{\hspace{2cm}}\times 10^{-2} \mathrm{M}​×10−2M. (Nearest integer)
Numerical answer
View written solutionFree

Correct answer: 57

  1. Find moles of NaOH in each solution

    Use: moles=M×V\text{moles} = M \times Vmoles=M×V where volume must be in litres.

    • For the first solution: V1=20 mL=0.020 LV_1 = 20\text{ mL} = 0.020\text{ L}V1​=20 mL=0.020 L M1=2 MM_1 = 2\text{ M}M1​=2 M n1=2×0.020=0.040 moln_1 = 2 \times 0.020 = 0.040\text{ mol}n1​=2×0.020=0.040 mol

    • For the second solution: V2=400 mL=0.400 LV_2 = 400\text{ mL} = 0.400\text{ L}V2​=400 mL=0.400 L M2=0.5 MM_2 = 0.5\text{ M}M2​=0.5 M n2=0.5×0.400=0.200 moln_2 = 0.5 \times 0.400 = 0.200\text{ mol}n2​=0.5×0.400=0.200 mol

  2. Total moles after mixing

    ntotal=0.040+0.200=0.240 moln_{\text{total}} = 0.040 + 0.200 = 0.240\text{ mol}ntotal​=0.040+0.200=0.240 mol

  3. Total volume after mixing

    Vtotal=20+400=420 mL=0.420 LV_{\text{total}} = 20 + 400 = 420\text{ mL} = 0.420\text{ L}Vtotal​=20+400=420 mL=0.420 L

  4. Final concentration

    Mfinal=ntotalVtotal=0.2400.420=0.5714 MM_{\text{final}} = \frac{n_{\text{total}}}{V_{\text{total}}} = \frac{0.240}{0.420} = 0.5714\text{ M}Mfinal​=Vtotal​ntotal​​=0.4200.240​=0.5714 M

  5. Express in the required form

    We need: ‾×10−2 M\underline{\hspace{1cm}} \times 10^{-2}\text{ M}​×10−2 M

    Since 0.5714 M=57.14×10−2 M0.5714\text{ M} = 57.14 \times 10^{-2}\text{ M}0.5714 M=57.14×10−2 M

    Nearest integer: 575757

  6. Comparison with stored answer

    Derived answer = 575757

    Stored correct answer = 575757

    Hence, they agree.

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