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Some Basic Concepts of Chemistry question

2020 · 6 Sep · Shift 1 · Q18
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  5. /2020 · 6 Sep · Shift 1 · Q18

Some Basic Concepts of Chemistry question

2020 · 6 Sep · Shift 1 · Q18

JEE MainChemistrySome Basic Concepts of ChemistryMCQ+4 / −1
A solution of two components containing n1n_1n1​ moles of the 1st component and n2n_2n2​ moles of the 2nd component is prepared. M1M_1M1​ and M2M_2M2​ are the molecular weights of component 1 and 2 respectively. If d is the density of the solution in g mL–1, C2C_2C2​ is the molarity and x2x_2x2​ is the mole fraction of the 2nd component, then C2C_2C2​ can be expressed as :
  1. A
    C2=1000x2M1+x2(M2−M1){C_2} = {{1000{x_2}} \over {{M_1} + {x_2}\left( {{M_2} - {M_1}} \right)}}C2​=M1​+x2​(M2​−M1​)1000x2​​
  2. B
    C2=1000dx2M1+x2(M2−M1){C_2} = {{1000d{x_2}} \over {{M_1} + {x_2}\left( {{M_2} - {M_1}} \right)}}C2​=M1​+x2​(M2​−M1​)1000dx2​​
  3. C
    C2=dx2M1+x2(M2−M1){C_2} = {{d{x_2}} \over {{M_1} + {x_2}\left( {{M_2} - {M_1}} \right)}}C2​=M1​+x2​(M2​−M1​)dx2​​
  4. D
    C2=dx1M1+x2(M2−M1){C_2} = {{d{x_1}} \over {{M_1} + {x_2}\left( {{M_2} - {M_1}} \right)}}C2​=M1​+x2​(M2​−M1​)dx1​​
View written solutionFree

Correct answer: B

  1. Write the definition of molarity

For component 2, C2=moles of component 2volume of solution in litresC_2=\frac{\text{moles of component 2}}{\text{volume of solution in litres}}C2​=volume of solution in litresmoles of component 2​

If the solution contains n1n_1n1​ moles of component 1 and n2n_2n2​ moles of component 2, then C2=n2V(in L)C_2=\frac{n_2}{V(\text{in L})}C2​=V(in L)n2​​

  1. Express solution volume using density

Total mass of solution is m=n1M1+n2M2m=n_1M_1+n_2M_2m=n1​M1​+n2​M2​ (in grams)

Given density ddd in g mL−1^{-1}−1, V(in mL)=md=n1M1+n2M2dV(\text{in mL})=\frac{m}{d}=\frac{n_1M_1+n_2M_2}{d}V(in mL)=dm​=dn1​M1​+n2​M2​​

So volume in litres is V(in L)=n1M1+n2M21000dV(\text{in L})=\frac{n_1M_1+n_2M_2}{1000d}V(in L)=1000dn1​M1​+n2​M2​​

Hence, C2=n2n1M1+n2M21000d=1000d n2n1M1+n2M2C_2=\frac{n_2}{\dfrac{n_1M_1+n_2M_2}{1000d}}=\frac{1000d\,n_2}{n_1M_1+n_2M_2}C2​=1000dn1​M1​+n2​M2​​n2​​=n1​M1​+n2​M2​1000dn2​​

  1. Use mole fraction of component 2

By definition, x2=n2n1+n2x_2=\frac{n_2}{n_1+n_2}x2​=n1​+n2​n2​​

Let total moles be n=n1+n2n=n_1+n_2n=n1​+n2​ Then, n2=x2n,n1=(1−x2)nn_2=x_2n, \qquad n_1=(1-x_2)nn2​=x2​n,n1​=(1−x2​)n

Substitute into the expression for C2C_2C2​: C2=1000d(x2n)(1−x2)nM1+x2nM2C_2=\frac{1000d(x_2n)}{(1-x_2)nM_1+x_2nM_2}C2​=(1−x2​)nM1​+x2​nM2​1000d(x2​n)​

Cancel nnn: C2=1000dx2(1−x2)M1+x2M2C_2=\frac{1000d x_2}{(1-x_2)M_1+x_2M_2}C2​=(1−x2​)M1​+x2​M2​1000dx2​​

  1. Simplify the denominator

(1−x2)M1+x2M2=M1−x2M1+x2M2(1-x_2)M_1+x_2M_2=M_1-x_2M_1+x_2M_2(1−x2​)M1​+x2​M2​=M1​−x2​M1​+x2​M2​ =M1+x2(M2−M1)=M_1+x_2(M_2-M_1)=M1​+x2​(M2​−M1​)

Therefore, C2=1000dx2M1+x2(M2−M1)C_2=\frac{1000d x_2}{M_1+x_2(M_2-M_1)}C2​=M1​+x2​(M2​−M1​)1000dx2​​

  1. Match with options

This matches Option B: C2=1000dx2M1+x2(M2−M1)\boxed{C_2=\frac{1000d x_2}{M_1+x_2(M_2-M_1)}}C2​=M1​+x2​(M2​−M1​)1000dx2​​​

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