JEE MainChemistrySome Basic Concepts of ChemistryMCQ+4 / −1
Experimentally it was found that a metal oxide has formula . Metal , present as and in its oxide. Fraction of the metal which exists as would be
- A7.01%
- B4.08%
- C6.05%
- D5.08%
View written solutionFree
Correct answer: B
- Interpret the formula
The oxide has formula .
This means for every oxygen atom, there are metal atoms.
Since oxygen is present as , total negative charge per formula unit is:
So, total positive charge from all metal ions together must be:
- Let the fraction of metal atoms present as be
Then fraction present as is:
Average oxidation state of metal will be:
- Use charge neutrality
There are metal atoms per oxygen atom.
Hence total positive charge contributed by metal ions is:
This must balance the charge of oxygen:
Solve:
So,
Thus, fraction of metal as is:
- Check options
- A: ❌
- B: ✅
- C: ❌
- D: ❌
- Final Answer
The fraction of metal existing as is:
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