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Some Basic Concepts of Chemistry question

2013 · Shift 0 · Q24
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Some Basic Concepts of Chemistry question

2013 · Shift 0 · Q24

JEE MainChemistrySome Basic Concepts of ChemistryMCQ+4 / −1
Experimentally it was found that a metal oxide has formula M0.98OM0.98OM0.98O. Metal MMM, present as M2+M^{2+}M2+ and M3+M^{3+}M3+ in its oxide. Fraction of the metal which exists as M3+M^{3+}M3+ would be
  1. A
    7.01%
  2. B
    4.08%
  3. C
    6.05%
  4. D
    5.08%
View written solutionFree

Correct answer: B

  1. Interpret the formula

The oxide has formula M0.98OM_{0.98}OM0.98​O.

This means for every 111 oxygen atom, there are 0.980.980.98 metal atoms.

Since oxygen is present as O2−O^{2-}O2−, total negative charge per formula unit is:

−2-2−2

So, total positive charge from all metal ions together must be:

+2+2+2


  1. Let the fraction of metal atoms present as M3+M^{3+}M3+ be xxx

Then fraction present as M2+M^{2+}M2+ is:

1−x1-x1−x

Average oxidation state of metal MMM will be:

2(1−x)+3x=2+x2(1-x) + 3x = 2 + x2(1−x)+3x=2+x


  1. Use charge neutrality

There are 0.980.980.98 metal atoms per oxygen atom.

Hence total positive charge contributed by metal ions is:

0.98(2+x)0.98(2+x)0.98(2+x)

This must balance the 2−2-2− charge of oxygen:

0.98(2+x)=20.98(2+x)=20.98(2+x)=2

Solve:

2+x=20.98=100492+x = \frac{2}{0.98} = \frac{100}{49}2+x=0.982​=49100​

So,

x=10049−2=100−9849=249x = \frac{100}{49}-2 = \frac{100-98}{49} = \frac{2}{49}x=49100​−2=49100−98​=492​

x≈0.0408x \approx 0.0408x≈0.0408

Thus, fraction of metal as M3+M^{3+}M3+ is:

0.0408×100=4.08%0.0408 \times 100 = 4.08\%0.0408×100=4.08%


  1. Check options
  • A: 7.01%7.01\%7.01% ❌
  • B: 4.08%4.08\%4.08% ✅
  • C: 6.05%6.05\%6.05% ❌
  • D: 5.08%5.08\%5.08% ❌

  1. Final Answer

The fraction of metal existing as M3+M^{3+}M3+ is:

4.08%\boxed{4.08\%}4.08%​

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