JEE MainChemistryHydrocarbonsMCQ+4 / −1
In the given reactions identify and 

- AA : n-Pentane B : Cis - 2 - butene
- BA : 2-Pentyne B : Cis-2-butene
- CA : n-Pentane B : trans-2-butene
- DA : 2-Pentyne B : trans-2-butene
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Correct answer: D
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The reaction sequence shown is not visible in the text, but from the answer choices we can infer:
- Compound is either -pentane or -pentyne.
- Compound is either cis-2-butene or trans-2-butene.
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A very standard organic conversion is:
- Dehydrohalogenation / alkylation steps giving an alkyne such as -pentyne.
- Reduction of an alkyne to an alkene.
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To decide :
- Partial reduction of an alkyne with dissolving metal conditions such as gives the trans-alkene.
- Partial reduction with Lindlar catalyst gives the cis-alkene.
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Since the choices pair an alkyne precursor with a butene product, the chemically consistent intermediate is -pentyne, not -pentane.
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Further, the standard selective reduction of an alkyne under dissolving metal conditions gives: Hence should be trans-2-butene.
-
Therefore the matching option is:
So, the correct option is D.
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