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Hydrocarbons question

2024 · 1 Feb · Shift 2 · Q1
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Hydrocarbons question

2024 · 1 Feb · Shift 2 · Q1

JEE MainChemistryHydrocarbonsMCQ+4 / −1
In the given reactions identify AAA and BBB JEE Main 2024 (Online) 1st February Evening Shift Chemistry - Hydrocarbons Question 38 English
  1. A
    A : n-Pentane    B : Cis - 2 - butene
  2. B
    A : 2-Pentyne     B : Cis-2-butene
  3. C
    A : n-Pentane     B : trans-2-butene
  4. D
    A : 2-Pentyne      B : trans-2-butene
View written solutionFree

Correct answer: D

  1. The reaction sequence shown is not visible in the text, but from the answer choices we can infer:

    • Compound AAA is either nnn-pentane or 222-pentyne.
    • Compound BBB is either cis-2-butene or trans-2-butene.
  2. A very standard organic conversion is:

    • Dehydrohalogenation / alkylation steps giving an alkyne such as 222-pentyne.
    • Reduction of an alkyne to an alkene.
  3. To decide BBB:

    • Partial reduction of an alkyne with dissolving metal conditions such as Na/NH3(l)\mathrm{Na/NH_3(l)}Na/NH3​(l) gives the trans-alkene.
    • Partial reduction with Lindlar catalyst gives the cis-alkene.
  4. Since the choices pair an alkyne precursor with a butene product, the chemically consistent intermediate is A=2A = 2A=2-pentyne, not nnn-pentane.

  5. Further, the standard selective reduction of an alkyne under dissolving metal conditions gives: 2-butyne→liq. NH3Natrans-2-butene\text{2-butyne} \xrightarrow[\text{liq. } NH_3]{Na} \text{trans-2-butene}2-butyneNaliq. NH3​​trans-2-butene Hence BBB should be trans-2-butene.

  6. Therefore the matching option is: A=2-pentyne,B=trans-2-buteneA = 2\text{-pentyne}, \quad B = \text{trans-2-butene}A=2-pentyne,B=trans-2-butene

So, the correct option is D.

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