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Hydrocarbons question

2016 · Shift 0 · Q5
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  5. /2016 · Shift 0 · Q5

Hydrocarbons question

2016 · Shift 0 · Q5

JEE MainChemistryHydrocarbonsMCQ+4 / −1
At 300 K and 1 atm, 15 mL of a gaseous hydrocarbon requires 375 mL air containing 20% O2O_2O2​ by volume for complete combustion. After combustion the gases occupy 345 mL. Assuming that the water formed is in liquid form and the volumes were measured at the same temperature and pressure, the formula of the hydrocarbon is:
  1. A
    C3H8C_3H_8C3​H8​
  2. B
    C4H8C_4H_8C4​H8​
  3. C
    C4H10C_4H_{10}C4​H10​
  4. D
    C3H6C_3H_6C3​H6​
View written solutionFree

Correct answer: A

  1. Let the hydrocarbon be CxHyC_xH_yCx​Hy​.

  2. Given volumes at same TTT and PPP, so volume ratios = mole ratios.

    • Hydrocarbon volume =15 mL= 15\,\text{mL}=15mL
    • Air used =375 mL= 375\,\text{mL}=375mL
    • Since air contains 20%20\%20% O2O_2O2​, oxygen volume supplied is 375×20100=75 mL375 \times \frac{20}{100} = 75\,\text{mL}375×10020​=75mL
  3. Combustion reaction: CxHy+(x+y4)O2→xCO2+y2H2OC_xH_y + \left(x + \frac{y}{4}\right)O_2 \rightarrow xCO_2 + \frac{y}{2}H_2OCx​Hy​+(x+4y​)O2​→xCO2​+2y​H2​O

    Since water is liquid, it does not contribute to final gas volume.

  4. Use oxygen consumption data

    For 15 mL15\,\text{mL}15mL hydrocarbon, oxygen required is 75 mL75\,\text{mL}75mL.

    So for 111 volume hydrocarbon, oxygen required is 7515=5 volumes\frac{75}{15} = 5 \text{ volumes}1575​=5 volumes

    Hence, x+y4=5x + \frac{y}{4} = 5x+4y​=5 4x+y=20...(1)4x + y = 20 \quad ...(1)4x+y=20...(1)

  5. Final gaseous volume after combustion

    Initial gases present before combustion:

    • Hydrocarbon = 151515 mL
    • O2=75O_2 = 75O2​=75 mL
    • N2N_2N2​ from air = 375−75=300375 - 75 = 300375−75=300 mL

    After combustion:

    • CO2=15xCO_2 = 15xCO2​=15x mL
    • Unreacted O2=0O_2 = 0O2​=0 mL (since required exactly for complete combustion)
    • N2=300N_2 = 300N2​=300 mL
    • Water is liquid, so ignored in gas volume

    Total final gas volume is given as 345345345 mL: 15x+300=34515x + 300 = 34515x+300=345 15x=4515x = 4515x=45 x=3x = 3x=3

  6. Find yyy using equation (1): 4x+y=204x + y = 204x+y=20 4(3)+y=204(3) + y = 204(3)+y=20 12+y=2012 + y = 2012+y=20 y=8y = 8y=8

  7. Therefore, the hydrocarbon is C3H8C_3H_8C3​H8​

  8. Check with options

    • A: C3H8C_3H_8C3​H8​ ✅
    • B: C4H8C_4H_8C4​H8​ ❌
    • C: C4H10C_4H_{10}C4​H10​ ❌
    • D: C3H6C_3H_6C3​H6​ ❌

So the correct option is A.

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