JEE MainChemistryHydrocarbonsMCQ+4 / −1
At 300 K and 1 atm, 15 mL of a gaseous hydrocarbon requires 375 mL air containing 20% by volume for complete combustion. After combustion the gases occupy 345 mL. Assuming that the water formed is in liquid form and the volumes were measured at the same temperature and pressure, the formula of the hydrocarbon is:
- A
- B
- C
- D
View written solutionFree
Correct answer: A
-
Let the hydrocarbon be .
-
Given volumes at same and , so volume ratios = mole ratios.
- Hydrocarbon volume
- Air used
- Since air contains , oxygen volume supplied is
-
Combustion reaction:
Since water is liquid, it does not contribute to final gas volume.
-
Use oxygen consumption data
For hydrocarbon, oxygen required is .
So for volume hydrocarbon, oxygen required is
Hence,
-
Final gaseous volume after combustion
Initial gases present before combustion:
- Hydrocarbon = mL
- mL
- from air = mL
After combustion:
- mL
- Unreacted mL (since required exactly for complete combustion)
- mL
- Water is liquid, so ignored in gas volume
Total final gas volume is given as mL:
-
Find using equation (1):
-
Therefore, the hydrocarbon is
-
Check with options
- A: ✅
- B: ❌
- C: ❌
- D: ❌
So the correct option is A.
More from Hydrocarbons
- 2–Hexyne gives trans–2–Hexene on treatment with :2012 · MCQ
- Which branched chain isomer of the hydrocarbon with molecular mass 72u gives only one isomer of mono substituted alkyl halide ?2012 · MCQ
- Ozonolysis of an organic compound gives formaldehyde as one of the products. This confirms the presence of :2011 · MCQ
- The main product of the following reaction is 2010 · MCQ
- In the following sequence of reactions, the alkene affords the compound ‘B’ A B The compound B is2008 · MCQ
- The treatment of with produces2008 · MCQ
- Toluene is nitrated and the resulting product is reduced with tin and hydrochloric acid. The product so obtained is diazotised and then heated with cuprous bromide. The reaction mixture so formed contains2008 · MCQ
- The hydrocarbon which can react with sodium in liquid ammonia is2008 · MCQ