- AIodoform test
- BSchiff's test
- CNinhydrin's test
- DTollen's test
View written solutionFree
Correct answer: A
- Identify the reaction of nitrile with Grignard reagent
A nitrile reacts with one equivalent of Grignard reagent to give an imine magnesium salt, which on hydrolysis gives a ketone.
For benzonitrile: On hydrolysis:
So the product is: This is acetophenone (methyl phenyl ketone), a yellow liquid.
- Test the product against the given options
(A) Iodoform test
Iodoform test is given by compounds containing the group: Acetophenone has the structure: So it contains a methyl ketone group and gives positive iodoform test.
(B) Schiff's test
Schiff's reagent gives positive test mainly with aldehydes. Acetophenone is a ketone, so this is negative.
(C) Ninhydrin's test
Ninhydrin test is given by amino acids / primary amines in special cases, not by acetophenone. So negative.
(D) Tollen's test
Tollen's reagent is reduced by aldehydes (and a few special compounds like formic acid, alpha-hydroxy ketones). Acetophenone does not give this test. So negative.
- Conclusion
The product is acetophenone, which gives a positive iodoform test.
Therefore, the correct option is:
- Comparison with stored correct answer
Stored correct answer: A
My derived answer: A
They agree.
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