JEE MainChemistryChemical Kinetics and Nuclear ChemistryNumerical+4 / −1
A molecule undergoes two independent first order reactions whose respective half lives are 12 min and 3 min. If both the reactions are occurring then the time taken for the 50% consumption of the reactant is min. (Nearest integer)
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Correct answer: 2
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For a first-order reaction, the rate constant is related to half-life by
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The molecule undergoes two independent first-order reactions simultaneously, so the overall rate constant is the sum:
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Compute the individual rate constants:
Thus,
- If both reactions are occurring, the reactant disappears with effective first-order constant . For 50% consumption, For a first-order process,
Substitute:
- Nearest integer:
Therefore, the required time is
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