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Chemical Kinetics and Nuclear Chemistry question

2022 · 28 Jun · Shift 2 · Q16
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Chemical Kinetics and Nuclear Chemistry question

2022 · 28 Jun · Shift 2 · Q16

JEE MainChemistryChemical Kinetics and Nuclear ChemistryNumerical+4 / −1
A radioactive element has a half life of 200 days. The percentage of original activity remaining after 83 days is ‾\underline{\hspace{2cm}}​. (Nearest integer) (Given : antilog 0.125 = 1.333, antilog 0.693 = 4.93)
Numerical answer
View written solutionFree

Correct answer: 75

  1. Use the radioactive decay relation

For activity of a radioactive substance:

A=A0e−λtA = A_0 e^{-\lambda t}A=A0​e−λt

Also, half-life is related to decay constant by:

t1/2=0.693λt_{1/2} = \frac{0.693}{\lambda}t1/2​=λ0.693​

Given:

t1/2=200 dayst_{1/2} = 200\ \text{days}t1/2​=200 days

So,

λ=0.693200\lambda = \frac{0.693}{200}λ=2000.693​

  1. Find the fraction of activity remaining after 83 days

AA0=e−λt=e−(0.693200)(83)\frac{A}{A_0} = e^{-\lambda t} = e^{-\left(\frac{0.693}{200}\right)(83)}A0​A​=e−λt=e−(2000.693​)(83)

AA0=e−0.287595\frac{A}{A_0} = e^{-0.287595}A0​A​=e−0.287595

Now convert to base 10 using:

e−x=10−x/2.303e^{-x} = 10^{-x/2.303}e−x=10−x/2.303

So,

AA0=10−0.287595/2.303\frac{A}{A_0} = 10^{-0.287595/2.303}A0​A​=10−0.287595/2.303

AA0=10−0.125\frac{A}{A_0} = 10^{-0.125}A0​A​=10−0.125

Given:

antilog 0.125=1.333\text{antilog } 0.125 = 1.333antilog 0.125=1.333

Hence,

10−0.125=1100.125=11.333≈0.7510^{-0.125} = \frac{1}{10^{0.125}} = \frac{1}{1.333} \approx 0.7510−0.125=100.1251​=1.3331​≈0.75

  1. Convert to percentage

% activity remaining=0.75×100=75%\%\text{ activity remaining} = 0.75 \times 100 = 75\%% activity remaining=0.75×100=75%

  1. Nearest integer

75\boxed{75}75​

  1. Comparison with stored answer

Stored correct answer = 757575

Our derived answer also = 757575

So the answer matches.

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