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Chemical Kinetics and Nuclear Chemistry question

2019 · 10 Apr · Shift 1 · Q14
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Chemical Kinetics and Nuclear Chemistry question

2019 · 10 Apr · Shift 1 · Q14

JEE MainChemistryChemical Kinetics and Nuclear ChemistryMCQ+4 / −1
A bacterial infection in an internal wound grows as N'(t) = N0 exp(t), where the time t is in hours. A does of antibiotic, taken orally, needs 1 hour to reach the wound. Once it reaches there, the bacterial population goes down as dNdt=−5N2{{dN} \over {dt}} = - 5{N^2}dtdN​=−5N2. What will be the plot of N0N{{{N_0}} \over N}NN0​​ vs. t after 1 hour?
  1. A
    JEE Main 2019 (Online) 10th April Morning Slot Chemistry - Chemical Kinetics and Nuclear Chemistry Question 138 English Option 1
  2. B
    JEE Main 2019 (Online) 10th April Morning Slot Chemistry - Chemical Kinetics and Nuclear Chemistry Question 138 English Option 2
  3. C
    JEE Main 2019 (Online) 10th April Morning Slot Chemistry - Chemical Kinetics and Nuclear Chemistry Question 138 English Option 3
  4. D
    JEE Main 2019 (Online) 10th April Morning Slot Chemistry - Chemical Kinetics and Nuclear Chemistry Question 138 English Option 4
View written solutionFree

Correct answer: D

  1. Interpret the statement carefully

    The bacterial population initially grows as N(t)=N0etN(t)=N_0 e^tN(t)=N0​et (the question writes N′(t)=N0etN'(t)=N_0 e^tN′(t)=N0​et, but from the context of population growth, this clearly means the population itself grows exponentially before the medicine acts).

    The antibiotic takes 1 hour to reach the wound. So at t=1t=1t=1 hour, the bacterial population is N(1)=N0e.N(1)=N_0 e.N(1)=N0​e.

  2. Dynamics after 1 hour

    For t>1t>1t>1, once the antibiotic reaches the wound, the population obeys dNdt=−5N2.\frac{dN}{dt}=-5N^2.dtdN​=−5N2.

    We solve this differential equation using separation of variables: dNN2=−5 dt.\frac{dN}{N^2}=-5\,dt.N2dN​=−5dt.

    Integrating, ∫N−2 dN=∫−5 dt\int N^{-2}\,dN=\int -5\,dt∫N−2dN=∫−5dt −1N=−5t+C.-\frac{1}{N}=-5t+C.−N1​=−5t+C.

    Rearranging, 1N=5t+C′.\frac{1}{N}=5t+C'.N1​=5t+C′.

  3. Apply the condition at t=1t=1t=1

    At t=1t=1t=1, N=N0e.N=N_0 e.N=N0​e. Hence, 1N0e=5(1)+C′\frac{1}{N_0 e}=5(1)+C'N0​e1​=5(1)+C′ C′=1N0e−5.C'=\frac{1}{N_0 e}-5.C′=N0​e1​−5.

    Therefore, 1N=5t+1N0e−5.\frac{1}{N}=5t+\frac{1}{N_0 e}-5.N1​=5t+N0​e1​−5.

  4. Find N0N\dfrac{N_0}{N}NN0​​ as a function of ttt

    Multiply both sides by N0N_0N0​: N0N=5N0t+1e−5N0.\frac{N_0}{N}=5N_0 t+\frac{1}{e}-5N_0.NN0​​=5N0​t+e1​−5N0​.

    So, N0N=5N0(t−1)+1e\boxed{\frac{N_0}{N}=5N_0(t-1)+\frac{1}{e}}NN0​​=5N0​(t−1)+e1​​ for t≥1t\ge 1t≥1.

  5. Nature of the plot

    This is a straight line in ttt with:

    • positive slope 5N05N_05N0​
    • value at t=1t=1t=1 equal to N0N(1)=N0N0e=1e.\frac{N_0}{N(1)}=\frac{N_0}{N_0 e}=\frac{1}{e}.N(1)N0​​=N0​eN0​​=e1​.

    So after 1 hour, the graph of N0N\dfrac{N_0}{N}NN0​​ vs. ttt is a linearly increasing straight line starting from (1,1e)\left(1,\frac{1}{e}\right)(1,e1​).

  6. Match with the option

    Hence the correct plot is the option showing an increasing straight line after t=1t=1t=1.

    Therefore, the correct answer is D.

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