JEE MainChemistryChemical Kinetics and Nuclear ChemistryMCQ+4 / −1
The rate of a reaction A doubles on increasing the temperature from 300 to 310 K. By how much, the temperature of reaction B should be Increased from 300 K so that rate doubles if activation energy of the reaction B is twice to that of reaction A.
- A9.84 K
- B4.92 K
- C2.45 K
- D19.67 K
View written solutionFree
Correct answer: B
- Use Arrhenius equation
For a reaction,
So for two temperatures, the ratio of rate constants is
Since rate doubles, we take
- For reaction A
Given reaction A doubles when temperature increases from K to K.
Thus,
- For reaction B
Activation energy of B is twice that of A:
Let the required temperature rise for B from K be . Then final temperature is
Again rate doubles, so
Substitute :
- Compare the two equations
From reaction A:
From reaction B:
Equating,
Cancel :
Now,
So,
Hence,
- Solve for
So,
Cross-multiply:
- Check options
The required increase in temperature is
So the correct option is B.
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