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Basics of Organic Chemistry question

2022 · 25 Jun · Shift 1 · Q10
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Basics of Organic Chemistry question

2022 · 25 Jun · Shift 1 · Q10

JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
The IUPAC name of ethylidene chloride is :
  1. A
    1-Chloroethene
  2. B
    1-Chloroethyne
  3. C
    1,2-Dichloroethane
  4. D
    1,1-Dichloroethane
View written solutionFree

Correct answer: D

  1. Interpret the common name

    The compound is ethylidene chloride.

    In common nomenclature:

    • ethylidene refers to the group CH3−CH<\mathrm{CH_3-CH<}CH3​−CH<
    • chloride here indicates that two chlorine atoms are attached to the same carbon of the ethylidene unit.

    So the structure is: CH3−CHCl2\mathrm{CH_3-CHCl_2}CH3​−CHCl2​

  2. Find the parent chain

    The longest carbon chain has 2 carbons, so the parent hydrocarbon is: ethane\mathrm{ethane}ethane

  3. Locate the substituents

    Both chlorine atoms are attached to the same carbon, i.e. carbon 1.

    Hence the IUPAC name is: 1,1-dichloroethane\mathrm{1,1\text{-}dichloroethane}1,1-dichloroethane

  4. Check the options

    • A: 1-Chloroethene →\rightarrow→ incorrect, this is an alkene with one chlorine.
    • B: 1-Chloroethyne →\rightarrow→ incorrect, this is an alkyne with one chlorine.
    • C: 1,2-Dichloroethane →\rightarrow→ incorrect, chlorines are on different carbons.
    • D: 1,1-Dichloroethane →\rightarrow→ correct.
  5. Conclusion

    The IUPAC name of ethylidene chloride is: 1,1-Dichloroethane\boxed{\mathrm{1,1\text{-}Dichloroethane}}1,1-Dichloroethane​

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