JEE MainChemistryAldehydes Ketones and Carboxylic AcidsNumerical+4 / −1
Number of compounds giving (i) red colouration with ceric ammonium nitrate and also (ii) positive iodoform test from the following is 

Numerical answer
View written solutionFree
Correct answer: 3
We need to count compounds which satisfy both:
- Red colouration with ceric ammonium nitrate (CAN)
- Positive iodoform test
1. What does ceric ammonium nitrate test indicate?
Ceric ammonium nitrate gives a red colouration with alcohols.
So the compound must contain an alcoholic group.
2. What does iodoform test indicate?
Iodoform test is given by compounds containing either:
- a methyl ketone group:
- or an alcohol of type:
- ethanol also gives the test because it gets oxidized to ethanal.
Since the compound must also give CAN test, we focus on alcohols that give iodoform test.
Thus the required alcohols are of type and also
3. Common compounds satisfying both tests
Among standard compounds in this chapter, the alcohols that satisfy both are:
-
Ethanol:
- CAN: positive
- Iodoform: positive
-
2-Propanol:
- CAN: positive
- Iodoform: positive
-
2-Butanol:
- CAN: positive
- Iodoform: positive
Hence, the number of such compounds is
4. Final answer
The required number of compounds is
5. Comparison with stored correct answer
Stored correct answer =
Our derived answer also = . So they agree.
More from Aldehydes Ketones and Carboxylic Acids
- Find out the major products from the following reaction sequence. Includes diagram2023 · MCQ
- A trisubstituted compound '', gives neutral test positive. Treatment of compound 'A' with and gives …2023 · Numerical
- What is the correct order of acidity of the protons marked in the given compounds ? Includes diagram2023 · MCQ
- Which of the following compounds would give the following set of qualitative analysis ? (i) Fehling's Test : Positive (ii) Na fusion extract upon treatment with sodium nitroprusside gives a blood red colour but not prussian blue.2023 · MCQ
- Number of compounds from the following which will not dissolve in cold and solutions but will dissolve in hot solution is . Includes diagram2023 · Numerical
- Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R. Assertion A: can be easily reduced using to Reason … Includes diagram2023 · MCQ
- Consider the following reaction The correct statement for product B is. It is Includes diagram2023 · MCQ
- The number of molecules which gives the haloform test among the following molecules is . Includes diagram2023 · Numerical