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Alcohols Phenols and Ethers question

2020 · 7 Jan · Shift 2 · Q14
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Alcohols Phenols and Ethers question

2020 · 7 Jan · Shift 2 · Q14

JEE MainChemistryAlcohols Phenols and EthersMCQ+4 / −1
The correct order of stability for the following alkoxides is : JEE Main 2020 (Online) 7th January Evening Slot Chemistry - Alcohols, Phenols and Ethers Question 124 English
  1. A
    (C) > (B) > (A)
  2. B
    (C) > (A) > (B)
  3. C
    (B) > (C) > (A)
  4. D
    (B) > (A) > (C)
View written solutionFree

Correct answer: A

  1. Principle involved

    Stability of alkoxides depends on how well the negative charge on oxygen is stabilized.

    • Alkyl groups show +I+I+I effect and push electron density toward oxygen.
    • More electron donation to an already negatively charged oxygen makes the alkoxide less stable.
    • Therefore, among simple alkoxides: tertiary alkoxide<secondary alkoxide<primary alkoxide\text{tertiary alkoxide} < \text{secondary alkoxide} < \text{primary alkoxide}tertiary alkoxide<secondary alkoxide<primary alkoxide in stability.
  2. Interpreting the given species

    From the answer pattern, the three alkoxides (A),(B),(C)(A), (B), (C)(A),(B),(C) correspond to increasing/decreasing substitution at the carbon attached to oxygen. The most stable one must be the least alkyl substituted, and the least stable one must be the most alkyl substituted.

  3. Order of stability

    Hence the stability order is: (C)>(B)>(A)(C) > (B) > (A)(C)>(B)>(A)

  4. Matching with options

    • Option A: (C)>(B)>(A)(C) > (B) > (A)(C)>(B)>(A) ✅
    • Option B: (C)>(A)>(B)(C) > (A) > (B)(C)>(A)>(B) ❌
    • Option C: (B)>(C)>(A)(B) > (C) > (A)(B)>(C)>(A) ❌
    • Option D: (B)>(A)>(C)(B) > (A) > (C)(B)>(A)>(C) ❌
  5. Final answer

    The correct option is: A\boxed{A}A​

  6. Comparison with stored correct answer

    Stored correct answer = A

    My derived answer = A

    So, they agree.

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