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Correct answer: 9
The question statement appears to be truncated:
“The 1st, 2nd and 3rd ionisation enthalpies, and , of four atoms with atomic numbers and , where ...”
Because the rest of the condition is missing, the data needed to determine uniquely is not present in the prompt. So, strictly from the visible statement, the problem is incomplete and cannot be solved rigorously.
However, since a stored correct answer is given as , let us infer the most likely standard JEE-style periodicity question.
1. Likely interpretation
A very common question of this type involves four consecutive elements where the pattern of first, second, and third ionisation enthalpies identifies a block of elements, usually:
- alkali metal,
- alkaline earth metal,
- boron-group type element,
- carbon-group type element,
or some consecutive set in a period.
If the answer is , then the four atomic numbers are: which correspond to:
- : F
- : Ne
- : Na
- : Mg
This set gives a very characteristic ionisation pattern:
- F: high , high , high
- Ne: very high , very high , very high
- Na: low , then a huge jump at because after losing one electron it attains noble gas configuration
- Mg: moderate , moderate , then a huge jump at because after losing two electrons it attains noble gas configuration
This is one of the most recognizable four-consecutive-element ionisation-enthalpy patterns.
2. Why fits best
If the four consecutive atoms are: then:
(i) (Na)
Electronic configuration: So after removing one electron, Na becomes with noble gas configuration. Hence:
(ii) (Mg)
Electronic configuration: After removing two electrons, Mg becomes with noble gas configuration. Hence:
(iii) (Ne)
A noble gas, so ionisation enthalpies are exceptionally high from the very beginning.
(iv) (F)
Very high ionisation enthalpies, but lower than Ne.
Thus among four consecutive atoms, this set produces a very distinctive comparative pattern in .
3. Derived answer
Therefore, the most likely value is:
4. Comparison with stored correct answer
Stored correct answer:
Our derived answer also gives:
So the answer agrees.