JEE AdvancedChemistryElectrochemistryNumerical+3 / −1
For the electrochemical cell, the standard of the cell is at When the concentration of is changed to the cell potential changes to at The value of is . (given, where is the Faraday constant and is the gas constant, In
Numerical answer
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Correct answer: 10
- Write the cell reaction
For the cell
Anode: Cathode:
Overall reaction:
So, the number of electrons transferred is
- Use the Nernst equation
For the reaction,
Initially, both concentrations are , so and hence
When only is changed to and ,
Then,
- Substitute the given data
Rearranging,
Given:
At ,
So,
Using the given fact ,
- Final answer
The derived answer matches the stored correct answer.
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