- AR is steam volatile.
- BQ gives dark violet coloration with 1% aqueous solution.
- CS gives yellow precipitate with 2, 4-dinitrophenylhydrazine.
- DS gives dark violet coloration with 1% aqueous solution.
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Correct answer: B, C
- Identify compound from cumene oxidation
Cumene undergoes air oxidation followed by acidic hydrolysis by the cumene process:
Since the next step is with (Reimer–Tiemann reaction), the reactive component must be phenol.
So,
- Reaction of phenol with
Phenol with undergoes Reimer–Tiemann reaction to give mainly o-hydroxybenzaldehyde and a small amount of p-hydroxybenzaldehyde.
Thus,
- Formation of from with
is -hydroxybenzaldehyde. In presence of , the phenolic forms phenoxide and reacts with benzyl bromide via Williamson ether synthesis:
So is o-benzyloxybenzaldehyde.
- Check each option
Option A: is steam volatile.
is -hydroxybenzaldehyde. Steam volatility is shown prominently by o-hydroxybenzaldehyde due to intramolecular H-bonding and lower association. The para isomer forms intermolecular H-bonding and is not steam volatile.
So, A is false.
Option B: gives dark violet coloration with 1% aqueous solution.
is -hydroxybenzaldehyde, which still contains a phenolic group. Phenols give colored complexes with neutral .
Hence, B is true.
Option C: gives yellow precipitate with 2,4-dinitrophenylhydrazine.
is -benzyloxybenzaldehyde. It contains an aldehyde group.
Aldehydes and ketones give yellow/orange precipitate with 2,4-DNP reagent.
Hence, C is true.
Option D: gives dark violet coloration with 1% aqueous solution.
In , the phenolic has been converted into a benzyl ether (). Therefore, there is no free phenolic group left.
So it will not give the coloration test.
Hence, D is false.
- Final answer
Correct statements are:
- Comparison with stored correct answer
Stored correct answer:
My derived answer matches it exactly.
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