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2023

59 questions · IIT JAM
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2023

59 questions · IIT JAM

Chemistry59 questions
Organic Reaction Mechanism and Synthetic ApplicationsChemistry · 12 questionsLiquid StateChemistry · 2 questionsElectrochemistryChemistry · 2 questionsAtomic and Molecular StructureChemistry · 4 questionsBioinorganic ChemistryChemistry · 2 questionsMain Group ElementsChemistry · 2 questionsAnalytical ChemistryChemistry · 2 questionsAromatic and Heterocyclic ChemistryChemistry · 2 questionsBasic Concepts and StereochemistryChemistry · 4 questionsAdsorptionChemistry · 1 questionsChemical and Phase EquilibriaChemistry · 3 questionsGaseous StateChemistry · 1 questionsChemical KineticsChemistry · 3 questionsSolid StateChemistry · 1 questionsTransition MetalsChemistry · 6 questionsChemical Bonding and Shapes of MoleculesChemistry · 4 questionsQualitative Organic AnalysisChemistry · 2 questionsChemical ThermodynamicsChemistry · 3 questionsExtractions of MetalsChemistry · 1 questionsNatural Products ChemistryChemistry · 1 questionsSpectroscopyChemistry · 1 questions
  1. Q1.The structure of Q in the following reaction scheme is Includes diagram
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · MCQ
  2. Q2.The major product of the reaction is (i) CH2​I2​ Zn-Cu (ii) Li, NH3 (liq.) (iii) H3​O+ Includes diagram
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · MCQ
  3. Q3.The rate of addition of 1-hexyl radical to the given molecules follows the order Includes diagram
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · MCQ
  4. Q4.The major product of the reaction is Includes diagram
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · MCQ
  5. Q5.The diagram that best describes the variation of viscosity (η) of water with temperature at 1 atm is
    Chemistry · Liquid State · MCQ
  6. Q6.The SI unit of the molar conductivity of an electrolyte solution is
    Chemistry · Electrochemistry · MCQ
  7. Q7.The system with the lowest zero-point energy when it is confined to a one-dimensional box of length L is
    Chemistry · Atomic and Molecular Structure · MCQ
  8. Q8.The metal ion present in human *carbonic anhydrase* is
    Chemistry · Bioinorganic Chemistry · MCQ
  9. Q9.The oxoacid of sulfur that has S−O2​−S bond is
    Chemistry · Main Group Elements · MCQ
  10. Q10.An alkaline (NaOH) solution of a compound produces a yellow colored solution on addition of NaBO₃. The compound is
    Chemistry · Analytical Chemistry · MCQ
  11. Q12.The major product in the following reaction is Includes diagram
    Chemistry · Aromatic and Heterocyclic Chemistry · MCQ
  12. Q13.The most stable conformation of Y and that of Z are Includes diagram
    Chemistry · Basic Concepts and Stereochemistry · MCQ
  13. Q14.The major product **Y** in the following reaction scheme is Includes diagram
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · MCQ
  14. Q15.The major product of the reaction is Includes diagram
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · MCQ
  15. Q16.The major product of the reaction is Includes diagram
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · MCQ
  16. Q17.Adsorption of a gas on a solid surface follows the Langmuir isotherm. If ka​/kd​=1.0 bar −1, the fraction of adsorption sites occupied by the gas at equilibrium under 2.0 bar pressure of the gas at 25 °C is (ka​ and kd​ are…
    Chemistry · Adsorption · MCQ
  17. Q18.The vapor pressure of a dilute solution of a non-volatile solute and the vapor pressure of the pure solvent at the same temperature are P and P∗, respectively. P∗P∗−P​ is equal to (Assume that the vapor phase…
    Chemistry · Chemical and Phase Equilibria · MCQ
  18. Q19.The volume of water (in mL) required to be added to a 100 mL solution (aq. 0.1 M) of a weak acid (HA) at 25 °C to double its degree of dissociation is [Given: Ka​ of HA at 25 °C = 1.8×10−5]
    Chemistry · Chemical and Phase Equilibria · MCQ
  19. Q20.The following diagram is obtained in a pH-metric titration of a weak dibasic acid (H₂A) with a strong base. The point that best represents [HA⁻] = [A⁻²] is Includes diagram
    Chemistry · Chemical and Phase Equilibria · MCQ
  20. Q21.Equal number of gas molecules **A** (mass m and radius r) and **B** (mass 2m and radius 2r) are placed in two separate containers of equal volume. At a given temperature, the ratio of the collision frequency of **B** to that of…
    Chemistry · Gaseous State · MCQ
  21. Q22.For the given elementary reactions, the steady-state concentration of X is 2Pk1​​Xk4​⇌k2​​​Q+R↓S​
    Chemistry · Chemical Kinetics · MCQ
  22. Q23.The separation (in nm) of {134} planes of an orthorhombic unit cell (with cell parameters a = 0.5 nm, b = 0.6 nm, and c = 0.8 nm) is
    Chemistry · Solid State · MCQ
  23. Q24.The transition metal (M) complex that can have all isomers (geometric, linkage, and ionization) is
    Chemistry · Transition Metals · MCQ
  24. Q25.The geometry of [VO(acac) 2​] is
    Chemistry · Transition Metals · MCQ
  25. Q26.The products **X** and **Y** in the following reaction sequence, respectively, are BCl3​NH4​Cl in C6​H5​Cl150∘C​XNaBH4​NaBH4​​Y
    Chemistry · Main Group Elements · MCQ
  26. Q27.The correct order of the energy of the d orbitals of a square planar complex is
    Chemistry · Transition Metals · MCQ
  27. Q28.X and Y in the following reactions, respectively, are EtOH+2H2​SO4​→X+H3​O++HSO4−​HNO3​+2H2​SO4​→Y+H3​O++2HSO4−​…
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · MCQ
  28. Q29.The correct order of energy levels of the molecular orbitals of N2​ is
    Chemistry · Chemical Bonding and Shapes of Molecules · MCQ
  29. Q30.Free heme in aqueous solution when exposed to dioxygen is finally converted to (circle around iron in the given choices represents the protoporphyrin IX)
    Chemistry · Bioinorganic Chemistry · MCQ
  30. Q31.Correct statement(s) about Q and R is/are Includes diagram
    Chemistry · Qualitative Organic Analysis · Multiple correct
  31. Q32.The correct statement(s) is/are
    Chemistry · Basic Concepts and Stereochemistry · Multiple correct
  32. Q33.The reaction(s) that yield(s) Ph-CH2-CH2-CO2Me as the major product is/are
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · Multiple correct
  33. Q34.The correct option(s) of the reagents required for the following reaction is/are Includes diagram
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · Multiple correct
  34. Q35.The reaction(s) that yield(s) 1-naphthol as the major product is/are
    Chemistry · Aromatic and Heterocyclic Chemistry · Multiple correct
  35. Q36.The correct relation(s) for an ideal gas in a closed system is/are
    Chemistry · Chemical Thermodynamics · Multiple correct
  36. Q37.The molecule(s) that follow(s) Ia​<Ib​=Ic​ (Ia​, Ib​, and Ic​ are the principal moments of inertia) is/are
    Chemistry · Atomic and Molecular Structure · Multiple correct
  37. Q38.The role(s) of fluorspar in the electrolytic reduction of Al2​O3​ is/are to
    Chemistry · Extractions of Metals · Multiple correct
  38. Q39.The correct statement(s) about the complexes **I** (K₃[CoF₆]) and **II** (K₃[RhF₆]) is/are
    Chemistry · Transition Metals · Multiple correct
  39. Q40.The diatomic molecule(s) that has/have bond order of one is/are
    Chemistry · Chemical Bonding and Shapes of Molecules · Multiple correct
  40. Q41.The molecular weight of the major product of the reaction is ​ (in integer). (i) Br₂ (excess), CH₃CO₂H (ii) Sn/HCl (iii) NaNO₂/HCl (excess), 0 °C (iv) CuBr (excess) [Given: atomic weight of H = 1, C = 12, N = 14,… Includes diagram
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · Numerical
  41. Q42.A 0.06 g/mL solution of (S)-1-phenylethanol placed in a 5 cm long polarimeter tube shows an optical rotation of 1.2°. The specific rotation is ​°. (round off to the nearest integer)
    Chemistry · Basic Concepts and Stereochemistry · Numerical
  42. Q43.The isoelectric point of glutamic acid is ​ (round off to two decimal places) Includes diagram
    Chemistry · Natural Products Chemistry · Numerical
  43. Q44.Consider the following reaction: 2C6​H6​+15O2​→12CO2​+6H2​OΔr​H2980​=−3120 kJ mol−1. A closed…
    Chemistry · Chemical Thermodynamics · Numerical
  44. Q45.For the elementary reaction C←k2​A→k1​B,k1​=2k2​. At time t=0, [A]=A0​ and [B]=[C]=0. At a later time t,…
    Chemistry · Chemical Kinetics · Numerical
  45. Q46.The highest possible energy of a photon in the emission spectrum of hydrogen atom is ​ eV. [Given: Rydberg constant = 13.61 eV] (round off to two decimal places)
    Chemistry · Atomic and Molecular Structure · Numerical
  46. Q47.The standard reduction potential (E0) of Fe 3+→ Fe is ​ V. [Given: Fe 3+→ Fe 2+E0 = 0.77 V and Fe 2+→ Fe E0 = -0.44 V] (round off to three decimal places)
    Chemistry · Electrochemistry · Numerical
  47. Q48.The number of valence electrons in Na 2​[Fe(CO) 4​] (the Colman's reagent) is ​.
    Chemistry · Transition Metals · Numerical
  48. Q49.In the Born-Haber cycle, the heat of formation of CuCl is ​ kJ/mol. [Given: Heat of atomization of Cu = +338 kJ/mol, Ionization energy of Cu = +746 kJ/mol, Heat of atomization of Cl 2​ = +121 kJ/mol, Electron…
    Chemistry · Chemical Bonding and Shapes of Molecules · Numerical
  49. Q50.The spin-only magnetic moment of B 2​ molecule is ​μB​. (round off to two decimal places)
    Chemistry · Chemical Bonding and Shapes of Molecules · Numerical
  50. Q51.The sum of the total number of stereoisomers (including enantiomers) present in the following molecules is ​. Includes diagram
    Chemistry · Basic Concepts and Stereochemistry · Numerical
  51. Q52.The number of singlets observed in the 1 H NMR spectrum of P is ​.
    Chemistry · Qualitative Organic Analysis · Numerical
  52. Q53.When a glass capillary tube is dipped in water, a 1.0 cm rise in the water level is observed at 18 °C. The internal radius of the capillary is ​ cm.
    Chemistry · Liquid State · Numerical
  53. Q54.The volume of 2.0 mol of an ideal gas is reduced to half isothermally at 300 K in a closed system. The value of ΔG is ​ kJ.
    Chemistry · Chemical Thermodynamics · Numerical
  54. Q55.The harmonic vibrational frequency of a diatomic molecule is 2000 cm⁻¹. Its zero-point energy is ​ eV.
    Chemistry · Spectroscopy · Numerical
  55. Q56.An elementary reaction 2A → P follows a second order rate law with rate constant 2.5 × 10⁻³ dm³ mol⁻¹ s⁻¹. The time required for the concentration of A to change from 0.4 mol dm⁻³ to 0.2 mol dm⁻³ is ​ s.
    Chemistry · Chemical Kinetics · Numerical
  56. Q57.The following diagram shows the kinetic energy of the ejected photoelectrons against the energy of incident radiation for two metal surfaces M₁ and M₂. If the energy of the incident radiation on M₁ is equal to the work function of M₂, the…
    Chemistry · Atomic and Molecular Structure · Numerical
  57. Q58.The spin-only magnetic moment of [Fe(acac)₃] is ​ μB.
    Chemistry · Transition Metals · Numerical
  58. Q59.The amount of ethane produced in the following reaction is ​ kg. C2​H4​(2 kg)+H2​(2 kg)Wilkinson’s Catalyst​C2​H6​ (90% catalytic conversion)…
    Chemistry · Organic Reaction Mechanism and Synthetic Applications · Numerical
  59. Q60.In a gravimetric estimation of Al, a sample of 0.1000 g AlCl3​ is precipitated with 8-hydroxyquinoline. The weight of the precipitate is ​ g.
    Chemistry · Analytical Chemistry · Numerical