IIT JAMChemistryTransition MetalsMCQ+2 / −0.67
The correct option having one complex from each of the following pairs which is more reactive towards the oxidative addition reaction by hydrogen molecule is
Pair 1: IrCl(PMe₃)₃ (I) and IrCl(CO)(PMe₃)₂ (II)
Pair 2: IrCl(CO)(PPh₃)₂ (III) and IrCl₃(PPh₃) (IV)
- A(I) and (III)
- B(I) and (IV)
- C(II) and (III)
- D(II) and (IV)
View written solutionFree
Correct answer: A
More from Transition Metals
- The value of n for the complex [Fe(CO)₄(SiMe₃)]ⁿ satisfying the 18-electron rule is .2019 · Numerical
- The correct order of wavelength (λmax) of the halide to metal charge-transfer band of [Co(NH3)5Cl]2+ (I), [Co(NH3)5Br]2+ (II) and [Co(NH3)5I]2+ (III), is2019 · MCQ
- Among the following metal carbonyl species, the one with the highest metal-carbon back bonding is2018 · MCQ
- The CORRECT order of (the octahedral crystal field splitting of d orbitals) values for the following anionic metal complexes is2018 · MCQ
- The number of possible isomers for [Pt(py)(NH₃)BrCl] is . (py is pyridine)2018 · Numerical
- The magnitude of crystal field stabilization energy (CFSE) of octahedral complex is 7680 cm . The wavelength at the maximum absorption () of this complex is nm…2018 · Numerical
- The homogeneous catalyst used in water-gas shift reaction is2017 · MCQ
- Nitrosyl ligand binds to d-metal atoms in linear and bent fashion and behaves, respectively, as2017 · MCQ