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Liquid State question

2021 · Q54
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Liquid State question

2021 · Q54

IIT JAMChemistryLiquid StateNumerical+2 / −0
The surface tension (γ\gammaγ) of a solution, prepared by mixing 0.02 mol of an organic acid in 1 L of pure water, is represented as γ∗−γ=Alog⁡(1+Bc)\gamma^* - \gamma = A \log(1 + Bc)γ∗−γ=Alog(1+Bc) γ∗\gamma^*γ∗ is the surface tension of pure water, A=0.03 N m−1A = 0.03 \text{ N m}^{-1}A=0.03 N m−1, B=50 mol−1 LB = 50 \text{ mol}^{-1} \text{ L}B=50 mol−1 L and ccc is concentration in mol L −1^{-1}−1. The excess concentration of the organic acid at the surface of the liquid, determined by Gibbs adsorption equation at 300 K is n×10−6 mol m−2n \times 10^{-6} \text{ mol m}^{-2}n×10−6 mol m−2. The value of nnn (rounded off to two decimal places) is ‾\underline{\hspace{2cm}}​. (Given: R=8.314 J K−1 mol−1R = 8.314 \text{ J K}^{-1} \text{ mol}^{-1}R=8.314 J K−1 mol−1)
Numerical answer
View written solutionFree

Correct answer: 2.60, 2.62

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