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Chemical Kinetics

23 questions · Chemistry · IIT JAM
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Chemical Kinetics

23 questions · Chemistry · IIT JAM

  1. The substances, A, B and C undergo chemical reactions according to the scheme given below. At time t=0, the [A]=0.11 M. Considering them to be first order reactions, the concentration of B (in M) at equilibrium is Includes diagram2025 · Q27 · MCQ
  2. For the reaction MeMe+KCNMeOH/H2​O​MeMeCH2​CH2​ if the concentration of KCN is increased four times, then the…2024 · Q3 · MCQ
  3. For a zero-order reaction P → Q, the concentration of P becomes half of its initial concentration in 30 minutes after starting the reaction. The concentration of P becomes zero at ​ minutes. (rounded off to the…2024 · Q43 · Numerical
  4. For the given elementary reactions, the steady-state concentration of X is 2Pk1​​Xk4​⇌k2​​​Q+R↓S​2023 · Q22 · MCQ
  5. For the elementary reaction C←k2​A→k1​B,k1​=2k2​. At time t=0, [A]=A0​ and [B]=[C]=0. At a later time t,…2023 · Q45 · Numerical
  6. An elementary reaction 2A → P follows a second order rate law with rate constant 2.5 × 10⁻³ dm³ mol⁻¹ s⁻¹. The time required for the concentration of A to change from 0.4 mol dm⁻³ to 0.2 mol dm⁻³ is ​ s.2023 · Q56 · Numerical
  7. For the reaction extH2​extPO2−​(aq)+extOH−(aq)→extHPO32−​(aq)+extH2​(g) the rate expression is k[extH2​extPO2−​][extOH−]2. If the concentration of extH2​extPO2−​ is doubled, the…2022 · Q9 · MCQ
  8. Half-life (t1/2​) of a chemical reaction varies with the initial concentration of reactant (Ao​) as given below: The order of the reaction is Includes table2021 · Q28 · MCQ
  9. For the consecutive reaction, XkX​​YkY​​Z C0​ is the initial concentration of X. The concentrations of X, Y and Z at time t are CX​, CY​ and CZ​, respectively. The expression for the…2021 · Q30 · MCQ
  10. For the reaction, Q+Rk1​k−1​​Xk2​​P k1​=2.5×105 L mol−1 s−1, k−1​=1.0×104 s−1 and k2​=10 s−1…2021 · Q59 · Numerical
  11. For the reaction shown in Scheme 1, the concentration profiles of different species are provided. Based on this graph, the correct condition(s) regarding the rate constants is(are) Includes diagram2020 · Q31 · Multiple correct
  12. For a reaction of the type A + B → Products, the unit of the rate constant is mol L⁻¹ s⁻¹. The overall order of the reaction is2019 · Q1 · MCQ
  13. The half-life of the chemical reaction, A → Product, for initial reactant concentrations of 0.1 and 0.4 mol L −1 are 200 and 50 s, respectively. The order of the reaction is2019 · Q15 · MCQ
  14. The turnover frequency (TOF) for the catalytic reaction, A (1 mol) Catalyst (0.01 mol)5 hours​ B with 90% yield of the product is ​ hour −1. (Round off to the nearest integer)2019 · Q56 · Numerical
  15. A radioactive sample decays to 10% of its initial amount in 4600 minutes. The rate constant of this process is ​ hour −1. (Round off to two decimal places)2019 · Q57 · Numerical
  16. The reaction, A ⟶ Products, follows first-order kinetics. If [A] represents the concentration of reactant at time t, the INCORRECT variation is shown in2018 · Q27 · MCQ
  17. The time for 50% completion of a zero order reaction is 30 min. Time for 80% completion of this reaction is2018 · Q46 · Numerical
  18. For a first order reaction A(g)→2B(g)+C(g), the rate constant in terms of initial pressure (p0​) and pressure at time t (pt​), is given by2017 · Q29 · MCQ
  19. For a reaction 2A+B→C+D, if rate of consumption of A is 0.1 mol L⁻¹s⁻¹, the rate of production of C (in mol L⁻¹s⁻¹) is2017 · Q50 · Numerical
  20. For a zero order reaction, the half-life depends on the initial concentration [C₀] of the reactant as2016 · Q27 · MCQ
  21. The rate constants for a reaction at 300 and 350 K are 8 and 160 L mol⁻¹ s⁻¹, respectively. The activation energy of the reaction in kJ mol⁻¹ is __. [Given R = 8.314 J K⁻¹ mol⁻¹]2016 · Q59 · Numerical
  22. The kinetics of the reaction 2N 2​ O 5​ → 4NO 2​ + O 2​ in liquid bromine medium was measured independently for three different initial concentrations of N 2​ O 5​: 0.11, 0.07 and 0.05 mol L −1. The half-life of the…2015 · Q26 · MCQ
  23. For a reaction, the rate constant at 25 °C is doubled when the temperature is raised to 45 °C. The activation energy (in kJ mol −1) of the reaction is ​ [Given: ln2 = 0.693]2015 · Q57 · Numerical